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(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(O,O′-dibenzyl dithiophosphate)
In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry abou...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961295/ https://www.ncbi.nlm.nih.gov/pubmed/21202177 http://dx.doi.org/10.1107/S1600536808008398 |
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author | Xie, Bin Zou, Li-Ke He, Yi-Guo Feng, Jian-Shen Zhang, Xiu-Lan |
author_facet | Xie, Bin Zou, Li-Ke He, Yi-Guo Feng, Jian-Shen Zhang, Xiu-Lan |
author_sort | Xie, Bin |
collection | PubMed |
description | In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four macrocyclic N atoms. The two O,O′-bis(2-phenylmethyl) dithiophosphate anions act as counter-ions to balance the charge and they interact with the complex through N—H⋯S hydrogen bonds. Important geometric data include Ni—N distances of 1.958 (3) and 1.963 (3) Å. |
format | Text |
id | pubmed-2961295 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29612952010-12-30 (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(O,O′-dibenzyl dithiophosphate) Xie, Bin Zou, Li-Ke He, Yi-Guo Feng, Jian-Shen Zhang, Xiu-Lan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four macrocyclic N atoms. The two O,O′-bis(2-phenylmethyl) dithiophosphate anions act as counter-ions to balance the charge and they interact with the complex through N—H⋯S hydrogen bonds. Important geometric data include Ni—N distances of 1.958 (3) and 1.963 (3) Å. International Union of Crystallography 2008-04-04 /pmc/articles/PMC2961295/ /pubmed/21202177 http://dx.doi.org/10.1107/S1600536808008398 Text en © Xie et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xie, Bin Zou, Li-Ke He, Yi-Guo Feng, Jian-Shen Zhang, Xiu-Lan (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(O,O′-dibenzyl dithiophosphate) |
title | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(O,O′-dibenzyl dithiophosphate) |
title_full | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(O,O′-dibenzyl dithiophosphate) |
title_fullStr | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(O,O′-dibenzyl dithiophosphate) |
title_full_unstemmed | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(O,O′-dibenzyl dithiophosphate) |
title_short | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(O,O′-dibenzyl dithiophosphate) |
title_sort | (meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(ii) bis(o,o′-dibenzyl dithiophosphate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961295/ https://www.ncbi.nlm.nih.gov/pubmed/21202177 http://dx.doi.org/10.1107/S1600536808008398 |
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