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(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) bis­(O,O′-dibenzyl dithio­phosphate)

In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry abou...

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Autores principales: Xie, Bin, Zou, Li-Ke, He, Yi-Guo, Feng, Jian-Shen, Zhang, Xiu-Lan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961295/
https://www.ncbi.nlm.nih.gov/pubmed/21202177
http://dx.doi.org/10.1107/S1600536808008398
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author Xie, Bin
Zou, Li-Ke
He, Yi-Guo
Feng, Jian-Shen
Zhang, Xiu-Lan
author_facet Xie, Bin
Zou, Li-Ke
He, Yi-Guo
Feng, Jian-Shen
Zhang, Xiu-Lan
author_sort Xie, Bin
collection PubMed
description In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four macrocyclic N atoms. The two O,O′-bis­(2-phenyl­meth­yl) dithio­phosphate anions act as counter-ions to balance the charge and they inter­act with the complex through N—H⋯S hydrogen bonds. Important geometric data include Ni—N distances of 1.958 (3) and 1.963 (3) Å.
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spelling pubmed-29612952010-12-30 (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) bis­(O,O′-dibenzyl dithio­phosphate) Xie, Bin Zou, Li-Ke He, Yi-Guo Feng, Jian-Shen Zhang, Xiu-Lan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four macrocyclic N atoms. The two O,O′-bis­(2-phenyl­meth­yl) dithio­phosphate anions act as counter-ions to balance the charge and they inter­act with the complex through N—H⋯S hydrogen bonds. Important geometric data include Ni—N distances of 1.958 (3) and 1.963 (3) Å. International Union of Crystallography 2008-04-04 /pmc/articles/PMC2961295/ /pubmed/21202177 http://dx.doi.org/10.1107/S1600536808008398 Text en © Xie et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xie, Bin
Zou, Li-Ke
He, Yi-Guo
Feng, Jian-Shen
Zhang, Xiu-Lan
(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) bis­(O,O′-dibenzyl dithio­phosphate)
title (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) bis­(O,O′-dibenzyl dithio­phosphate)
title_full (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) bis­(O,O′-dibenzyl dithio­phosphate)
title_fullStr (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) bis­(O,O′-dibenzyl dithio­phosphate)
title_full_unstemmed (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) bis­(O,O′-dibenzyl dithio­phosphate)
title_short (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(II) bis­(O,O′-dibenzyl dithio­phosphate)
title_sort (meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)nickel(ii) bis­(o,o′-dibenzyl dithio­phosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961295/
https://www.ncbi.nlm.nih.gov/pubmed/21202177
http://dx.doi.org/10.1107/S1600536808008398
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