Methyl 4-amino-3-methyl­benzoate

In the mol­ecule of the title compound, C(9)H(11)NO(2), the methyl C and amino N atoms bonded to the benzene ring lie in the ring plane. Intra­molecular C—H⋯O hydrogen bonding results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 2.73 (3)° with respect to...

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Detalles Bibliográficos
Autores principales: Li, Xiang, Yuan, Lian-Shan, Wang, Dan, Liu, Shan, Yao, Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961297/
https://www.ncbi.nlm.nih.gov/pubmed/21202370
http://dx.doi.org/10.1107/S1600536808006223
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author Li, Xiang
Yuan, Lian-Shan
Wang, Dan
Liu, Shan
Yao, Cheng
author_facet Li, Xiang
Yuan, Lian-Shan
Wang, Dan
Liu, Shan
Yao, Cheng
author_sort Li, Xiang
collection PubMed
description In the mol­ecule of the title compound, C(9)H(11)NO(2), the methyl C and amino N atoms bonded to the benzene ring lie in the ring plane. Intra­molecular C—H⋯O hydrogen bonding results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 2.73 (3)° with respect to the benzene ring, so they are nearly coplanar. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains elongated along the c axis and stacked along the b axis.
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spelling pubmed-29612972010-12-30 Methyl 4-amino-3-methyl­benzoate Li, Xiang Yuan, Lian-Shan Wang, Dan Liu, Shan Yao, Cheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(9)H(11)NO(2), the methyl C and amino N atoms bonded to the benzene ring lie in the ring plane. Intra­molecular C—H⋯O hydrogen bonding results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 2.73 (3)° with respect to the benzene ring, so they are nearly coplanar. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains elongated along the c axis and stacked along the b axis. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961297/ /pubmed/21202370 http://dx.doi.org/10.1107/S1600536808006223 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xiang
Yuan, Lian-Shan
Wang, Dan
Liu, Shan
Yao, Cheng
Methyl 4-amino-3-methyl­benzoate
title Methyl 4-amino-3-methyl­benzoate
title_full Methyl 4-amino-3-methyl­benzoate
title_fullStr Methyl 4-amino-3-methyl­benzoate
title_full_unstemmed Methyl 4-amino-3-methyl­benzoate
title_short Methyl 4-amino-3-methyl­benzoate
title_sort methyl 4-amino-3-methyl­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961297/
https://www.ncbi.nlm.nih.gov/pubmed/21202370
http://dx.doi.org/10.1107/S1600536808006223
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AT yuanlianshan methyl4amino3methylbenzoate
AT wangdan methyl4amino3methylbenzoate
AT liushan methyl4amino3methylbenzoate
AT yaocheng methyl4amino3methylbenzoate

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