3,5,7-Tripropyl-1-aza­adamantane-4,6,10-triol

The title compound, C(18)H(33)NO(3), was prepared according to a highly diastereoselective hydrogenation procedure from 3,5,7-triallyl-1-aza­adamantane-4,6,10-trione. The crystal structure of the title compound contains two crystallographically independent mol­ecules (Z′ = 2), which are linked by in...

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Detalles Bibliográficos
Autores principales: Saaidi, Pierre-Loïc, Chazal, Pierre-Etienne, Maurin, Philippe, Jeanneau, Erwann, Hasserodt, Jens
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961298/
https://www.ncbi.nlm.nih.gov/pubmed/21202295
http://dx.doi.org/10.1107/S1600536808006284
Descripción
Sumario:The title compound, C(18)H(33)NO(3), was prepared according to a highly diastereoselective hydrogenation procedure from 3,5,7-triallyl-1-aza­adamantane-4,6,10-trione. The crystal structure of the title compound contains two crystallographically independent mol­ecules (Z′ = 2), which are linked by inter­molecular hydrogen bonding into chains. In contrast to the aza­adamantanones, the aza­adamantanetriol core of the title compound does not show any particular C—C bond elongation.

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