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μ-Pyrazine-bis[tetraaquacadmium(II)] μ-pyrazine-bis[tetraacetatocadmium(II)]
In the title dinuclear ionic complex, [Cd(2)(C(4)H(4)N(2))(H(2)O)(8)][Cd(2)(CH(3)CO(2))(8)(C(4)H(4)N(2))], the cation and anion are disordered equally over a site with symmetry mmm. The Cd(II) ions and the N atoms of the bridging pyrazine ligand lie on the intersection of two crystallographic mirro...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961302/ https://www.ncbi.nlm.nih.gov/pubmed/21202258 http://dx.doi.org/10.1107/S1600536808010994 |
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author | Fun, Hoong-Kun Chantrapromma, Suchada Marandi, Farzin |
author_facet | Fun, Hoong-Kun Chantrapromma, Suchada Marandi, Farzin |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title dinuclear ionic complex, [Cd(2)(C(4)H(4)N(2))(H(2)O)(8)][Cd(2)(CH(3)CO(2))(8)(C(4)H(4)N(2))], the cation and anion are disordered equally over a site with symmetry mmm. The Cd(II) ions and the N atoms of the bridging pyrazine ligand lie on the intersection of two crystallographic mirror planes. The C atoms of the bridging pyrazine ligand lie on one of these mirror planes, and the acetate groups and water molecules lie across the intersecting mirror planes. Each Cd(II) atom in the cation is five-coordinated by four O atoms from four water molecules and one N atom from the bridging pyrazine ligand, whereas each Cd(II) in the anion is nine-coordinated by four pairs of O atoms from the bidentate acetate ligands and one N atom from the bridging pyrazine ligand. In the crystal structure, each anion is surrounded by eight nearest-neighbour cations and vice versa. The crystal structure is stabilized by ionic interactions as well as by C—H⋯O interactions. |
format | Text |
id | pubmed-2961302 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613022010-12-30 μ-Pyrazine-bis[tetraaquacadmium(II)] μ-pyrazine-bis[tetraacetatocadmium(II)] Fun, Hoong-Kun Chantrapromma, Suchada Marandi, Farzin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear ionic complex, [Cd(2)(C(4)H(4)N(2))(H(2)O)(8)][Cd(2)(CH(3)CO(2))(8)(C(4)H(4)N(2))], the cation and anion are disordered equally over a site with symmetry mmm. The Cd(II) ions and the N atoms of the bridging pyrazine ligand lie on the intersection of two crystallographic mirror planes. The C atoms of the bridging pyrazine ligand lie on one of these mirror planes, and the acetate groups and water molecules lie across the intersecting mirror planes. Each Cd(II) atom in the cation is five-coordinated by four O atoms from four water molecules and one N atom from the bridging pyrazine ligand, whereas each Cd(II) in the anion is nine-coordinated by four pairs of O atoms from the bidentate acetate ligands and one N atom from the bridging pyrazine ligand. In the crystal structure, each anion is surrounded by eight nearest-neighbour cations and vice versa. The crystal structure is stabilized by ionic interactions as well as by C—H⋯O interactions. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961302/ /pubmed/21202258 http://dx.doi.org/10.1107/S1600536808010994 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fun, Hoong-Kun Chantrapromma, Suchada Marandi, Farzin μ-Pyrazine-bis[tetraaquacadmium(II)] μ-pyrazine-bis[tetraacetatocadmium(II)] |
title | μ-Pyrazine-bis[tetraaquacadmium(II)] μ-pyrazine-bis[tetraacetatocadmium(II)] |
title_full | μ-Pyrazine-bis[tetraaquacadmium(II)] μ-pyrazine-bis[tetraacetatocadmium(II)] |
title_fullStr | μ-Pyrazine-bis[tetraaquacadmium(II)] μ-pyrazine-bis[tetraacetatocadmium(II)] |
title_full_unstemmed | μ-Pyrazine-bis[tetraaquacadmium(II)] μ-pyrazine-bis[tetraacetatocadmium(II)] |
title_short | μ-Pyrazine-bis[tetraaquacadmium(II)] μ-pyrazine-bis[tetraacetatocadmium(II)] |
title_sort | μ-pyrazine-bis[tetraaquacadmium(ii)] μ-pyrazine-bis[tetraacetatocadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961302/ https://www.ncbi.nlm.nih.gov/pubmed/21202258 http://dx.doi.org/10.1107/S1600536808010994 |
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