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Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
In the title mononuclear complex, [Cu(C(8)H(7)O(2))Cl(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is coordinated by one carboxylate O atom from a monodentate 4-methylbenzoate ligand, two N atoms from the 1,10-phenanthroline ligand, one chloride ion and one water molecule in a square-pyramidal geometry...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961304/ https://www.ncbi.nlm.nih.gov/pubmed/21202243 http://dx.doi.org/10.1107/S1600536808010945 |
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author | Song, Wen-Dong Wang, Hao Miao, Yan-Li |
author_facet | Song, Wen-Dong Wang, Hao Miao, Yan-Li |
author_sort | Song, Wen-Dong |
collection | PubMed |
description | In the title mononuclear complex, [Cu(C(8)H(7)O(2))Cl(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is coordinated by one carboxylate O atom from a monodentate 4-methylbenzoate ligand, two N atoms from the 1,10-phenanthroline ligand, one chloride ion and one water molecule in a square-pyramidal geometry. The crystal structure exhibits inter- and intramolecular C—H⋯Cl, C—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds, as well as C—H⋯π interactions of phenanthroline and methyl H atoms towards the π-systems of neighboring 4-methylbenzoate units and the pyridine rings of the phenanthroline system [centroid–centroid distances are 2.706 (2) and 2.992 (1) Å, respectively]. |
format | Text |
id | pubmed-2961304 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613042010-12-30 Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Song, Wen-Dong Wang, Hao Miao, Yan-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Cu(C(8)H(7)O(2))Cl(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is coordinated by one carboxylate O atom from a monodentate 4-methylbenzoate ligand, two N atoms from the 1,10-phenanthroline ligand, one chloride ion and one water molecule in a square-pyramidal geometry. The crystal structure exhibits inter- and intramolecular C—H⋯Cl, C—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds, as well as C—H⋯π interactions of phenanthroline and methyl H atoms towards the π-systems of neighboring 4-methylbenzoate units and the pyridine rings of the phenanthroline system [centroid–centroid distances are 2.706 (2) and 2.992 (1) Å, respectively]. International Union of Crystallography 2008-04-26 /pmc/articles/PMC2961304/ /pubmed/21202243 http://dx.doi.org/10.1107/S1600536808010945 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Song, Wen-Dong Wang, Hao Miao, Yan-Li Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) |
title | Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full | Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_fullStr | Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full_unstemmed | Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_short | Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_sort | aquachlorido(4-methylbenzoato-κo)(1,10-phenanthroline-κ(2)
n,n′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961304/ https://www.ncbi.nlm.nih.gov/pubmed/21202243 http://dx.doi.org/10.1107/S1600536808010945 |
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