Cargando…

Aqua­chlorido(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title mononuclear complex, [Cu(C(8)H(7)O(2))Cl(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is coordinated by one carboxylate O atom from a monodentate 4-methyl­benzoate ligand, two N atoms from the 1,10-phenanthroline ligand, one chloride ion and one water mol­ecule in a square-pyramidal geometry...

Descripción completa

Detalles Bibliográficos
Autores principales: Song, Wen-Dong, Wang, Hao, Miao, Yan-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961304/
https://www.ncbi.nlm.nih.gov/pubmed/21202243
http://dx.doi.org/10.1107/S1600536808010945
_version_ 1782188950637510656
author Song, Wen-Dong
Wang, Hao
Miao, Yan-Li
author_facet Song, Wen-Dong
Wang, Hao
Miao, Yan-Li
author_sort Song, Wen-Dong
collection PubMed
description In the title mononuclear complex, [Cu(C(8)H(7)O(2))Cl(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is coordinated by one carboxylate O atom from a monodentate 4-methyl­benzoate ligand, two N atoms from the 1,10-phenanthroline ligand, one chloride ion and one water mol­ecule in a square-pyramidal geometry. The crystal structure exhibits inter- and intra­molecular C—H⋯Cl, C—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds, as well as C—H⋯π inter­actions of phenanthroline and methyl H atoms towards the π-systems of neighboring 4-methyl­benzoate units and the pyridine rings of the phenanthroline system [centroid–centroid distances are 2.706 (2) and 2.992 (1) Å, respectively].
format Text
id pubmed-2961304
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29613042010-12-30 Aqua­chlorido(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Song, Wen-Dong Wang, Hao Miao, Yan-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Cu(C(8)H(7)O(2))Cl(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is coordinated by one carboxylate O atom from a monodentate 4-methyl­benzoate ligand, two N atoms from the 1,10-phenanthroline ligand, one chloride ion and one water mol­ecule in a square-pyramidal geometry. The crystal structure exhibits inter- and intra­molecular C—H⋯Cl, C—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds, as well as C—H⋯π inter­actions of phenanthroline and methyl H atoms towards the π-systems of neighboring 4-methyl­benzoate units and the pyridine rings of the phenanthroline system [centroid–centroid distances are 2.706 (2) and 2.992 (1) Å, respectively]. International Union of Crystallography 2008-04-26 /pmc/articles/PMC2961304/ /pubmed/21202243 http://dx.doi.org/10.1107/S1600536808010945 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Wen-Dong
Wang, Hao
Miao, Yan-Li
Aqua­chlorido(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title Aqua­chlorido(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Aqua­chlorido(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Aqua­chlorido(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Aqua­chlorido(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Aqua­chlorido(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort aqua­chlorido(4-methyl­benzoato-κo)(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961304/
https://www.ncbi.nlm.nih.gov/pubmed/21202243
http://dx.doi.org/10.1107/S1600536808010945
work_keys_str_mv AT songwendong aquachlorido4methylbenzoatoko110phenanthrolinek2nncopperii
AT wanghao aquachlorido4methylbenzoatoko110phenanthrolinek2nncopperii
AT miaoyanli aquachlorido4methylbenzoatoko110phenanthrolinek2nncopperii