μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]

In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal–bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C—H⋯S hydrogen bonds.

Detalles Bibliográficos
Autores principales: Avila, Vanessa, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961305/
https://www.ncbi.nlm.nih.gov/pubmed/21202218
http://dx.doi.org/10.1107/S1600536808010003
Descripción
Sumario:In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal–bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C—H⋯S hydrogen bonds.

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