μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]

In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal–bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C—H⋯S hydrogen bonds.

Detalles Bibliográficos
Autores principales: Avila, Vanessa, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961305/
https://www.ncbi.nlm.nih.gov/pubmed/21202218
http://dx.doi.org/10.1107/S1600536808010003
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author Avila, Vanessa
Tiekink, Edward R. T.
author_facet Avila, Vanessa
Tiekink, Edward R. T.
author_sort Avila, Vanessa
collection PubMed
description In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal–bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C—H⋯S hydrogen bonds.
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spelling pubmed-29613052010-12-30 μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)] Avila, Vanessa Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal–bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C—H⋯S hydrogen bonds. International Union of Crystallography 2008-04-18 /pmc/articles/PMC2961305/ /pubmed/21202218 http://dx.doi.org/10.1107/S1600536808010003 Text en © Avila and Tiekink 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Avila, Vanessa
Tiekink, Edward R. T.
μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_full μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_fullStr μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_full_unstemmed μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_short μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis­[bis­(N,N-diisopropyl­dithio­carbamato-κ(2) S,S′)zinc(II)]
title_sort μ-1,2-di-4-pyridylethane-κ(2) n:n′-bis­[bis­(n,n-diisopropyl­dithio­carbamato-κ(2) s,s′)zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961305/
https://www.ncbi.nlm.nih.gov/pubmed/21202218
http://dx.doi.org/10.1107/S1600536808010003
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AT tiekinkedwardrt m12di4pyridylethanek2nnbisbisnndiisopropyldithiocarbamatok2sszincii

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