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2,5,7-Trimethyl-3-phenylsulfonyl-1-benzofuran
The title compound, C(17)H(16)O(3)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring exhibits a dihedral angle of 81.16 (4)° with the plane of the benzofuran fragment. The crystal structure is stabilized by π–π inter...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961306/ https://www.ncbi.nlm.nih.gov/pubmed/21202286 http://dx.doi.org/10.1107/S1600536808008477 |
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author | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_facet | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_sort | Choi, Hong Dae |
collection | PubMed |
description | The title compound, C(17)H(16)O(3)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring exhibits a dihedral angle of 81.16 (4)° with the plane of the benzofuran fragment. The crystal structure is stabilized by π–π interactions between the furan and benzene rings of neighbouring molecules [centroid–centroid distance = 3.874 (2) Å] and by C—H⋯π interactions between a phenyl H atom of the phenylsulfonyl substituent and the furan ring of adjacent molecules. In addition, the crystal structure exhibits intra- and intermolecular C—H⋯O interactions. |
format | Text |
id | pubmed-2961306 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613062010-12-30 2,5,7-Trimethyl-3-phenylsulfonyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(16)O(3)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring exhibits a dihedral angle of 81.16 (4)° with the plane of the benzofuran fragment. The crystal structure is stabilized by π–π interactions between the furan and benzene rings of neighbouring molecules [centroid–centroid distance = 3.874 (2) Å] and by C—H⋯π interactions between a phenyl H atom of the phenylsulfonyl substituent and the furan ring of adjacent molecules. In addition, the crystal structure exhibits intra- and intermolecular C—H⋯O interactions. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961306/ /pubmed/21202286 http://dx.doi.org/10.1107/S1600536808008477 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk 2,5,7-Trimethyl-3-phenylsulfonyl-1-benzofuran |
title | 2,5,7-Trimethyl-3-phenylsulfonyl-1-benzofuran |
title_full | 2,5,7-Trimethyl-3-phenylsulfonyl-1-benzofuran |
title_fullStr | 2,5,7-Trimethyl-3-phenylsulfonyl-1-benzofuran |
title_full_unstemmed | 2,5,7-Trimethyl-3-phenylsulfonyl-1-benzofuran |
title_short | 2,5,7-Trimethyl-3-phenylsulfonyl-1-benzofuran |
title_sort | 2,5,7-trimethyl-3-phenylsulfonyl-1-benzofuran |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961306/ https://www.ncbi.nlm.nih.gov/pubmed/21202286 http://dx.doi.org/10.1107/S1600536808008477 |
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