Diethyl 2-[(1-methyl-1H-pyrrol-2-yl)methyl­ene­amino]-5-(2-thienylmethyl­ene­amino)thio­phene-3,4-dicarboxyl­ate

Both imine bonds of the title compound, C(21)H(21)N(3)O(4)S(2), were found to be in the E configuration. The terminal pyrrole and thio­phene rings are twisted by 2.5 (3) and 2.3 (2)°, respectively, from the mean plane of the central thio­phene to which they are attached. The structure is disordered...

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Detalles Bibliográficos
Autores principales: Dufresne, Stéphane, Skene, W. G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961309/
https://www.ncbi.nlm.nih.gov/pubmed/21202275
http://dx.doi.org/10.1107/S160053680800799X
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author Dufresne, Stéphane
Skene, W. G.
author_facet Dufresne, Stéphane
Skene, W. G.
author_sort Dufresne, Stéphane
collection PubMed
description Both imine bonds of the title compound, C(21)H(21)N(3)O(4)S(2), were found to be in the E configuration. The terminal pyrrole and thio­phene rings are twisted by 2.5 (3) and 2.3 (2)°, respectively, from the mean plane of the central thio­phene to which they are attached. The structure is disordered by exchange of the terminal heterocyclic rings; the site occupancy factors are ca 0.8 and 0.2. The crystal packing involves some π–π stacking [3.449 (4) Å between pyrrole and terminal thio­phene rings].
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spelling pubmed-29613092010-12-30 Diethyl 2-[(1-methyl-1H-pyrrol-2-yl)methyl­ene­amino]-5-(2-thienylmethyl­ene­amino)thio­phene-3,4-dicarboxyl­ate Dufresne, Stéphane Skene, W. G. Acta Crystallogr Sect E Struct Rep Online Organic Papers Both imine bonds of the title compound, C(21)H(21)N(3)O(4)S(2), were found to be in the E configuration. The terminal pyrrole and thio­phene rings are twisted by 2.5 (3) and 2.3 (2)°, respectively, from the mean plane of the central thio­phene to which they are attached. The structure is disordered by exchange of the terminal heterocyclic rings; the site occupancy factors are ca 0.8 and 0.2. The crystal packing involves some π–π stacking [3.449 (4) Å between pyrrole and terminal thio­phene rings]. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961309/ /pubmed/21202275 http://dx.doi.org/10.1107/S160053680800799X Text en © Dufresne and Skene 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dufresne, Stéphane
Skene, W. G.
Diethyl 2-[(1-methyl-1H-pyrrol-2-yl)methyl­ene­amino]-5-(2-thienylmethyl­ene­amino)thio­phene-3,4-dicarboxyl­ate
title Diethyl 2-[(1-methyl-1H-pyrrol-2-yl)methyl­ene­amino]-5-(2-thienylmethyl­ene­amino)thio­phene-3,4-dicarboxyl­ate
title_full Diethyl 2-[(1-methyl-1H-pyrrol-2-yl)methyl­ene­amino]-5-(2-thienylmethyl­ene­amino)thio­phene-3,4-dicarboxyl­ate
title_fullStr Diethyl 2-[(1-methyl-1H-pyrrol-2-yl)methyl­ene­amino]-5-(2-thienylmethyl­ene­amino)thio­phene-3,4-dicarboxyl­ate
title_full_unstemmed Diethyl 2-[(1-methyl-1H-pyrrol-2-yl)methyl­ene­amino]-5-(2-thienylmethyl­ene­amino)thio­phene-3,4-dicarboxyl­ate
title_short Diethyl 2-[(1-methyl-1H-pyrrol-2-yl)methyl­ene­amino]-5-(2-thienylmethyl­ene­amino)thio­phene-3,4-dicarboxyl­ate
title_sort diethyl 2-[(1-methyl-1h-pyrrol-2-yl)methyl­ene­amino]-5-(2-thienylmethyl­ene­amino)thio­phene-3,4-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961309/
https://www.ncbi.nlm.nih.gov/pubmed/21202275
http://dx.doi.org/10.1107/S160053680800799X
work_keys_str_mv AT dufresnestephane diethyl21methyl1hpyrrol2ylmethyleneamino52thienylmethyleneaminothiophene34dicarboxylate
AT skenewg diethyl21methyl1hpyrrol2ylmethyleneamino52thienylmethyleneaminothiophene34dicarboxylate

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