Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) dichloro­methane hemisolvate

The title compound, [CoCl(2)(C(21)H(17)ClN(2))]·0.5CH(2)Cl(2), crystallizes from dichloro­methane as a 2:1 solvate [CoCl(2)L](2)·CH(2)Cl(2) (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl(2) L mol­ecules in the asymmetric unit and both mol­ecules have similar conformati...

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Detalles Bibliográficos
Autores principales: Yang, Yue, Yang, Peiju, Zhang, Cui, Wu, Biao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961318/
https://www.ncbi.nlm.nih.gov/pubmed/21202178
http://dx.doi.org/10.1107/S1600536808007320
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author Yang, Yue
Yang, Peiju
Zhang, Cui
Wu, Biao
author_facet Yang, Yue
Yang, Peiju
Zhang, Cui
Wu, Biao
author_sort Yang, Yue
collection PubMed
description The title compound, [CoCl(2)(C(21)H(17)ClN(2))]·0.5CH(2)Cl(2), crystallizes from dichloro­methane as a 2:1 solvate [CoCl(2)L](2)·CH(2)Cl(2) (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl(2) L mol­ecules in the asymmetric unit and both mol­ecules have similar conformations. They are connected by a weak C—H⋯π inter­action involving the mesityl ring. The cobalt center is four-coordinated by the two N-atom donors of the bidentate ligand and two chloride ions in a distorted tetra­hedral geometry. The packing of the mol­ecules is stabilized by weak slipped π–π stacking inter­actions between symmetry-related phenanthroline groups.
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spelling pubmed-29613182010-12-30 Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) dichloro­methane hemisolvate Yang, Yue Yang, Peiju Zhang, Cui Wu, Biao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CoCl(2)(C(21)H(17)ClN(2))]·0.5CH(2)Cl(2), crystallizes from dichloro­methane as a 2:1 solvate [CoCl(2)L](2)·CH(2)Cl(2) (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl(2) L mol­ecules in the asymmetric unit and both mol­ecules have similar conformations. They are connected by a weak C—H⋯π inter­action involving the mesityl ring. The cobalt center is four-coordinated by the two N-atom donors of the bidentate ligand and two chloride ions in a distorted tetra­hedral geometry. The packing of the mol­ecules is stabilized by weak slipped π–π stacking inter­actions between symmetry-related phenanthroline groups. International Union of Crystallography 2008-04-04 /pmc/articles/PMC2961318/ /pubmed/21202178 http://dx.doi.org/10.1107/S1600536808007320 Text en © Yang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Yue
Yang, Peiju
Zhang, Cui
Wu, Biao
Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) dichloro­methane hemisolvate
title Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) dichloro­methane hemisolvate
title_full Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) dichloro­methane hemisolvate
title_fullStr Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) dichloro­methane hemisolvate
title_full_unstemmed Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) dichloro­methane hemisolvate
title_short Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) dichloro­methane hemisolvate
title_sort dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ(2) n,n′)cobalt(ii) dichloro­methane hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961318/
https://www.ncbi.nlm.nih.gov/pubmed/21202178
http://dx.doi.org/10.1107/S1600536808007320
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AT zhangcui dichlorido2chloro9mesityl110phenanthrolinek2nncobaltiidichloromethanehemisolvate
AT wubiao dichlorido2chloro9mesityl110phenanthrolinek2nncobaltiidichloromethanehemisolvate

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