Bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(II)–toluene–tetra­hydro­furan (4/2/1)

The transamination reaction of (2-pyridylmeth­yl)(triiso­propyl­silyl)amine with bis­{bis­(trimethyl­silyl)amido}zinc(II) yields the colorless title solvate, [Zn(C(15)H(27)N(2)Si)(2)]·0.5C(7)H(8)·0.25C(4)H(8)O. The title compound was crystallized from toluene and tetra­hydro­furan. There are two ind...

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Detalles Bibliográficos
Autores principales: Koch, Christian, Görls, Helmar, Westerhausen, Matthias
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961323/
https://www.ncbi.nlm.nih.gov/pubmed/21202207
http://dx.doi.org/10.1107/S160053680800888X
Descripción
Sumario:The transamination reaction of (2-pyridylmeth­yl)(triiso­propyl­silyl)amine with bis­{bis­(trimethyl­silyl)amido}zinc(II) yields the colorless title solvate, [Zn(C(15)H(27)N(2)Si)(2)]·0.5C(7)H(8)·0.25C(4)H(8)O. The title compound was crystallized from toluene and tetra­hydro­furan. There are two independent mol­ecules in the asymmetric unit. In each mol­ecule, the Zn atom is tetra­hedrally coordinated by four N atoms. The two mol­ecules differ in the orientation of the isopropyl groups. The mol­ecules show large N—Zn—N angles [143.0 (2) and 145.7 (2)° between the amide groups].

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