Bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(II)–toluene–tetra­hydro­furan (4/2/1)

The transamination reaction of (2-pyridylmeth­yl)(triiso­propyl­silyl)amine with bis­{bis­(trimethyl­silyl)amido}zinc(II) yields the colorless title solvate, [Zn(C(15)H(27)N(2)Si)(2)]·0.5C(7)H(8)·0.25C(4)H(8)O. The title compound was crystallized from toluene and tetra­hydro­furan. There are two ind...

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Detalles Bibliográficos
Autores principales: Koch, Christian, Görls, Helmar, Westerhausen, Matthias
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961323/
https://www.ncbi.nlm.nih.gov/pubmed/21202207
http://dx.doi.org/10.1107/S160053680800888X
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author Koch, Christian
Görls, Helmar
Westerhausen, Matthias
author_facet Koch, Christian
Görls, Helmar
Westerhausen, Matthias
author_sort Koch, Christian
collection PubMed
description The transamination reaction of (2-pyridylmeth­yl)(triiso­propyl­silyl)amine with bis­{bis­(trimethyl­silyl)amido}zinc(II) yields the colorless title solvate, [Zn(C(15)H(27)N(2)Si)(2)]·0.5C(7)H(8)·0.25C(4)H(8)O. The title compound was crystallized from toluene and tetra­hydro­furan. There are two independent mol­ecules in the asymmetric unit. In each mol­ecule, the Zn atom is tetra­hedrally coordinated by four N atoms. The two mol­ecules differ in the orientation of the isopropyl groups. The mol­ecules show large N—Zn—N angles [143.0 (2) and 145.7 (2)° between the amide groups].
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spelling pubmed-29613232010-12-30 Bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(II)–toluene–tetra­hydro­furan (4/2/1) Koch, Christian Görls, Helmar Westerhausen, Matthias Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The transamination reaction of (2-pyridylmeth­yl)(triiso­propyl­silyl)amine with bis­{bis­(trimethyl­silyl)amido}zinc(II) yields the colorless title solvate, [Zn(C(15)H(27)N(2)Si)(2)]·0.5C(7)H(8)·0.25C(4)H(8)O. The title compound was crystallized from toluene and tetra­hydro­furan. There are two independent mol­ecules in the asymmetric unit. In each mol­ecule, the Zn atom is tetra­hedrally coordinated by four N atoms. The two mol­ecules differ in the orientation of the isopropyl groups. The mol­ecules show large N—Zn—N angles [143.0 (2) and 145.7 (2)° between the amide groups]. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961323/ /pubmed/21202207 http://dx.doi.org/10.1107/S160053680800888X Text en © Koch et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Koch, Christian
Görls, Helmar
Westerhausen, Matthias
Bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(II)–toluene–tetra­hydro­furan (4/2/1)
title Bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(II)–toluene–tetra­hydro­furan (4/2/1)
title_full Bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(II)–toluene–tetra­hydro­furan (4/2/1)
title_fullStr Bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(II)–toluene–tetra­hydro­furan (4/2/1)
title_full_unstemmed Bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(II)–toluene–tetra­hydro­furan (4/2/1)
title_short Bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(II)–toluene–tetra­hydro­furan (4/2/1)
title_sort bis[(2-pyridylmeth­yl)(triisopropyl­silyl)amido]zinc(ii)–toluene–tetra­hydro­furan (4/2/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961323/
https://www.ncbi.nlm.nih.gov/pubmed/21202207
http://dx.doi.org/10.1107/S160053680800888X
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AT gorlshelmar bis2pyridylmethyltriisopropylsilylamidozinciitoluenetetrahydrofuran421
AT westerhausenmatthias bis2pyridylmethyltriisopropylsilylamidozinciitoluenetetrahydrofuran421

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