Methyl 2-(2-hydroxy­benzyl­ideneamino)-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carboxyl­ate

In the title compound, C(17)H(17)NO(3)S, the cyclohexene ring is essentially planar, with a maximum deviation of 0.006 (1) Å. The cyclo­hexene ring adopts a half-chair conformation. The dihedral angle between the thio­phene and benzene rings is 29.7 (1)°. The mol­ecular structure exhibits intra­mole...

Descripción completa

Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Karaca, Selvi, Asiri, Abdullah Mohamed, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961328/
https://www.ncbi.nlm.nih.gov/pubmed/21202355
http://dx.doi.org/10.1107/S1600536808010489
_version_ 1782188956415164416
author Akkurt, Mehmet
Karaca, Selvi
Asiri, Abdullah Mohamed
Büyükgüngör, Orhan
author_facet Akkurt, Mehmet
Karaca, Selvi
Asiri, Abdullah Mohamed
Büyükgüngör, Orhan
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, C(17)H(17)NO(3)S, the cyclohexene ring is essentially planar, with a maximum deviation of 0.006 (1) Å. The cyclo­hexene ring adopts a half-chair conformation. The dihedral angle between the thio­phene and benzene rings is 29.7 (1)°. The mol­ecular structure exhibits intra­molecular O—H⋯O, O—H⋯N and C—H⋯S hydrogen bonds, which generate one S(5) and two S(6) motifs. There is also a C—H⋯π inter­action between the cyclo­hexene ring system and the π-system of the benzene ring.
format Text
id pubmed-2961328
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29613282010-12-30 Methyl 2-(2-hydroxy­benzyl­ideneamino)-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carboxyl­ate Akkurt, Mehmet Karaca, Selvi Asiri, Abdullah Mohamed Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(17)NO(3)S, the cyclohexene ring is essentially planar, with a maximum deviation of 0.006 (1) Å. The cyclo­hexene ring adopts a half-chair conformation. The dihedral angle between the thio­phene and benzene rings is 29.7 (1)°. The mol­ecular structure exhibits intra­molecular O—H⋯O, O—H⋯N and C—H⋯S hydrogen bonds, which generate one S(5) and two S(6) motifs. There is also a C—H⋯π inter­action between the cyclo­hexene ring system and the π-system of the benzene ring. International Union of Crystallography 2008-04-18 /pmc/articles/PMC2961328/ /pubmed/21202355 http://dx.doi.org/10.1107/S1600536808010489 Text en © Akkurt et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Karaca, Selvi
Asiri, Abdullah Mohamed
Büyükgüngör, Orhan
Methyl 2-(2-hydroxy­benzyl­ideneamino)-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carboxyl­ate
title Methyl 2-(2-hydroxy­benzyl­ideneamino)-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carboxyl­ate
title_full Methyl 2-(2-hydroxy­benzyl­ideneamino)-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carboxyl­ate
title_fullStr Methyl 2-(2-hydroxy­benzyl­ideneamino)-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carboxyl­ate
title_full_unstemmed Methyl 2-(2-hydroxy­benzyl­ideneamino)-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carboxyl­ate
title_short Methyl 2-(2-hydroxy­benzyl­ideneamino)-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carboxyl­ate
title_sort methyl 2-(2-hydroxy­benzyl­ideneamino)-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961328/
https://www.ncbi.nlm.nih.gov/pubmed/21202355
http://dx.doi.org/10.1107/S1600536808010489
work_keys_str_mv AT akkurtmehmet methyl22hydroxybenzylideneamino4567tetrahydro1benzothiophene3carboxylate
AT karacaselvi methyl22hydroxybenzylideneamino4567tetrahydro1benzothiophene3carboxylate
AT asiriabdullahmohamed methyl22hydroxybenzylideneamino4567tetrahydro1benzothiophene3carboxylate
AT buyukgungororhan methyl22hydroxybenzylideneamino4567tetrahydro1benzothiophene3carboxylate

Ejemplares similares