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Pyromellitic acid–sarcosine (1/2)
The title compound, C(10)H(6)O(8)·2C(3)H(7)NO(2), crystallizes as an adduct with the acid and amino acid molecules in their neutral forms. The asymmetric unit contains one half of a centrosymmetric pyromellitic acid molecule and one sarcosine molecule. The sarcosine has the amine group protonated...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961339/ https://www.ncbi.nlm.nih.gov/pubmed/21202315 http://dx.doi.org/10.1107/S1600536808009045 |
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author | Domingos, Sérgio R. Ramos Silva, Manuela Martins, Nuno D. Matos Beja, Ana Paixão, J. A. |
author_facet | Domingos, Sérgio R. Ramos Silva, Manuela Martins, Nuno D. Matos Beja, Ana Paixão, J. A. |
author_sort | Domingos, Sérgio R. |
collection | PubMed |
description | The title compound, C(10)H(6)O(8)·2C(3)H(7)NO(2), crystallizes as an adduct with the acid and amino acid molecules in their neutral forms. The asymmetric unit contains one half of a centrosymmetric pyromellitic acid molecule and one sarcosine molecule. The sarcosine has the amine group protonated and the carboxyl group deprotonated, as is usual for amino acids (zwitterionic form). The pyromellitic acid molecules retain the four carboxyl H atoms with the carboxyl groups rotated out of the ring plane [O—C—C—C torsion angles = 24.1 (3) and 61.6 (2)°]. There is a three-dimensional hydrogen-bond network linking the molecules. |
format | Text |
id | pubmed-2961339 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613392010-12-30 Pyromellitic acid–sarcosine (1/2) Domingos, Sérgio R. Ramos Silva, Manuela Martins, Nuno D. Matos Beja, Ana Paixão, J. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(6)O(8)·2C(3)H(7)NO(2), crystallizes as an adduct with the acid and amino acid molecules in their neutral forms. The asymmetric unit contains one half of a centrosymmetric pyromellitic acid molecule and one sarcosine molecule. The sarcosine has the amine group protonated and the carboxyl group deprotonated, as is usual for amino acids (zwitterionic form). The pyromellitic acid molecules retain the four carboxyl H atoms with the carboxyl groups rotated out of the ring plane [O—C—C—C torsion angles = 24.1 (3) and 61.6 (2)°]. There is a three-dimensional hydrogen-bond network linking the molecules. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961339/ /pubmed/21202315 http://dx.doi.org/10.1107/S1600536808009045 Text en © Domingos et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Domingos, Sérgio R. Ramos Silva, Manuela Martins, Nuno D. Matos Beja, Ana Paixão, J. A. Pyromellitic acid–sarcosine (1/2) |
title | Pyromellitic acid–sarcosine (1/2) |
title_full | Pyromellitic acid–sarcosine (1/2) |
title_fullStr | Pyromellitic acid–sarcosine (1/2) |
title_full_unstemmed | Pyromellitic acid–sarcosine (1/2) |
title_short | Pyromellitic acid–sarcosine (1/2) |
title_sort | pyromellitic acid–sarcosine (1/2) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961339/ https://www.ncbi.nlm.nih.gov/pubmed/21202315 http://dx.doi.org/10.1107/S1600536808009045 |
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