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Pyromellitic acid–sarcosine (1/2)

The title compound, C(10)H(6)O(8)·2C(3)H(7)NO(2), crystallizes as an adduct with the acid and amino acid mol­ecules in their neutral forms. The asymmetric unit contains one half of a centrosymmetric pyromellitic acid mol­ecule and one sarcosine mol­ecule. The sarcosine has the amine group protonated...

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Autores principales: Domingos, Sérgio R., Ramos Silva, Manuela, Martins, Nuno D., Matos Beja, Ana, Paixão, J. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961339/
https://www.ncbi.nlm.nih.gov/pubmed/21202315
http://dx.doi.org/10.1107/S1600536808009045
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author Domingos, Sérgio R.
Ramos Silva, Manuela
Martins, Nuno D.
Matos Beja, Ana
Paixão, J. A.
author_facet Domingos, Sérgio R.
Ramos Silva, Manuela
Martins, Nuno D.
Matos Beja, Ana
Paixão, J. A.
author_sort Domingos, Sérgio R.
collection PubMed
description The title compound, C(10)H(6)O(8)·2C(3)H(7)NO(2), crystallizes as an adduct with the acid and amino acid mol­ecules in their neutral forms. The asymmetric unit contains one half of a centrosymmetric pyromellitic acid mol­ecule and one sarcosine mol­ecule. The sarcosine has the amine group protonated and the carboxyl group deprotonated, as is usual for amino acids (zwitterionic form). The pyromellitic acid mol­ecules retain the four carboxyl H atoms with the carboxyl groups rotated out of the ring plane [O—C—C—C torsion angles = 24.1 (3) and 61.6 (2)°]. There is a three-dimensional hydrogen-bond network linking the mol­ecules.
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spelling pubmed-29613392010-12-30 Pyromellitic acid–sarcosine (1/2) Domingos, Sérgio R. Ramos Silva, Manuela Martins, Nuno D. Matos Beja, Ana Paixão, J. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(6)O(8)·2C(3)H(7)NO(2), crystallizes as an adduct with the acid and amino acid mol­ecules in their neutral forms. The asymmetric unit contains one half of a centrosymmetric pyromellitic acid mol­ecule and one sarcosine mol­ecule. The sarcosine has the amine group protonated and the carboxyl group deprotonated, as is usual for amino acids (zwitterionic form). The pyromellitic acid mol­ecules retain the four carboxyl H atoms with the carboxyl groups rotated out of the ring plane [O—C—C—C torsion angles = 24.1 (3) and 61.6 (2)°]. There is a three-dimensional hydrogen-bond network linking the mol­ecules. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961339/ /pubmed/21202315 http://dx.doi.org/10.1107/S1600536808009045 Text en © Domingos et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Domingos, Sérgio R.
Ramos Silva, Manuela
Martins, Nuno D.
Matos Beja, Ana
Paixão, J. A.
Pyromellitic acid–sarcosine (1/2)
title Pyromellitic acid–sarcosine (1/2)
title_full Pyromellitic acid–sarcosine (1/2)
title_fullStr Pyromellitic acid–sarcosine (1/2)
title_full_unstemmed Pyromellitic acid–sarcosine (1/2)
title_short Pyromellitic acid–sarcosine (1/2)
title_sort pyromellitic acid–sarcosine (1/2)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961339/
https://www.ncbi.nlm.nih.gov/pubmed/21202315
http://dx.doi.org/10.1107/S1600536808009045
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