Di-μ-chlorido-bis­{chlorido[2-(2-furyl­methyl­imino­meth­yl)pyridine-κ(2) N,N′]nickel(II)}

The title dinuclear nickel(II) complex, [Ni(2)Cl(4)(C(11)H(10)N(2)O)(2)], lies on a centre of symmetry located at the centroid of the four-membered ring formed by the two Ni atoms and the bridging chloride ions. The Ni(II) atom is five-coordinated in a square-pyramidal geometry by the imine and pyri...

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Detalles Bibliográficos
Autores principales: Xia, Dong-Sheng, Chen, Wu, Tang, Xin-Long, Zeng, Qing-Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961345/
https://www.ncbi.nlm.nih.gov/pubmed/21202517
http://dx.doi.org/10.1107/S1600536808015183
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author Xia, Dong-Sheng
Chen, Wu
Tang, Xin-Long
Zeng, Qing-Fu
author_facet Xia, Dong-Sheng
Chen, Wu
Tang, Xin-Long
Zeng, Qing-Fu
author_sort Xia, Dong-Sheng
collection PubMed
description The title dinuclear nickel(II) complex, [Ni(2)Cl(4)(C(11)H(10)N(2)O)(2)], lies on a centre of symmetry located at the centroid of the four-membered ring formed by the two Ni atoms and the bridging chloride ions. The Ni(II) atom is five-coordinated in a square-pyramidal geometry by the imine and pyridine N atoms of the Schiff base ligand, and by one terminal and two bridging Cl atoms. The Ni⋯Ni distance is 3.506 (2) Å. The O atom of the furan substituent in the ligand unit is not involved in coordination to the Ni atom.
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spelling pubmed-29613452010-12-30 Di-μ-chlorido-bis­{chlorido[2-(2-furyl­methyl­imino­meth­yl)pyridine-κ(2) N,N′]nickel(II)} Xia, Dong-Sheng Chen, Wu Tang, Xin-Long Zeng, Qing-Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear nickel(II) complex, [Ni(2)Cl(4)(C(11)H(10)N(2)O)(2)], lies on a centre of symmetry located at the centroid of the four-membered ring formed by the two Ni atoms and the bridging chloride ions. The Ni(II) atom is five-coordinated in a square-pyramidal geometry by the imine and pyridine N atoms of the Schiff base ligand, and by one terminal and two bridging Cl atoms. The Ni⋯Ni distance is 3.506 (2) Å. The O atom of the furan substituent in the ligand unit is not involved in coordination to the Ni atom. International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961345/ /pubmed/21202517 http://dx.doi.org/10.1107/S1600536808015183 Text en © Xia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xia, Dong-Sheng
Chen, Wu
Tang, Xin-Long
Zeng, Qing-Fu
Di-μ-chlorido-bis­{chlorido[2-(2-furyl­methyl­imino­meth­yl)pyridine-κ(2) N,N′]nickel(II)}
title Di-μ-chlorido-bis­{chlorido[2-(2-furyl­methyl­imino­meth­yl)pyridine-κ(2) N,N′]nickel(II)}
title_full Di-μ-chlorido-bis­{chlorido[2-(2-furyl­methyl­imino­meth­yl)pyridine-κ(2) N,N′]nickel(II)}
title_fullStr Di-μ-chlorido-bis­{chlorido[2-(2-furyl­methyl­imino­meth­yl)pyridine-κ(2) N,N′]nickel(II)}
title_full_unstemmed Di-μ-chlorido-bis­{chlorido[2-(2-furyl­methyl­imino­meth­yl)pyridine-κ(2) N,N′]nickel(II)}
title_short Di-μ-chlorido-bis­{chlorido[2-(2-furyl­methyl­imino­meth­yl)pyridine-κ(2) N,N′]nickel(II)}
title_sort di-μ-chlorido-bis­{chlorido[2-(2-furyl­methyl­imino­meth­yl)pyridine-κ(2) n,n′]nickel(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961345/
https://www.ncbi.nlm.nih.gov/pubmed/21202517
http://dx.doi.org/10.1107/S1600536808015183
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AT tangxinlong dimchloridobischlorido22furylmethyliminomethylpyridinek2nnnickelii
AT zengqingfu dimchloridobischlorido22furylmethyliminomethylpyridinek2nnnickelii

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