Benzyl 3-[(E)-benzyl­idene]dithio­carbazate

Crystals of the title compound, C(15)H(14)N(2)S(2), were obtained from a condensation reaction of benzyl dithio­carbazate and benzaldehyde. The mol­ecule assumes an E configuration about the N=C double bond. The phenyl ring of the thio­ester group is nearly perpendicular to the dithio­carbazate plan...

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Detalles Bibliográficos
Autores principales: Shan, Shang, Tian, Yu-Liang, Wang, Shan-Heng, Wang, Wen-Long, Xu, Ying-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961347/
https://www.ncbi.nlm.nih.gov/pubmed/21202539
http://dx.doi.org/10.1107/S1600536808012944
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author Shan, Shang
Tian, Yu-Liang
Wang, Shan-Heng
Wang, Wen-Long
Xu, Ying-Li
author_facet Shan, Shang
Tian, Yu-Liang
Wang, Shan-Heng
Wang, Wen-Long
Xu, Ying-Li
author_sort Shan, Shang
collection PubMed
description Crystals of the title compound, C(15)H(14)N(2)S(2), were obtained from a condensation reaction of benzyl dithio­carbazate and benzaldehyde. The mol­ecule assumes an E configuration about the N=C double bond. The phenyl ring of the thio­ester group is nearly perpendicular to the dithio­carbazate plane, with a dihedral angle of 84.60 (5)°. In the crystal structure, inter­molecular N—H⋯S hydrogen bonding links adjacent mol­ecules to form a centrosymmetric supra­molecular dimer.
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spelling pubmed-29613472010-12-30 Benzyl 3-[(E)-benzyl­idene]dithio­carbazate Shan, Shang Tian, Yu-Liang Wang, Shan-Heng Wang, Wen-Long Xu, Ying-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(15)H(14)N(2)S(2), were obtained from a condensation reaction of benzyl dithio­carbazate and benzaldehyde. The mol­ecule assumes an E configuration about the N=C double bond. The phenyl ring of the thio­ester group is nearly perpendicular to the dithio­carbazate plane, with a dihedral angle of 84.60 (5)°. In the crystal structure, inter­molecular N—H⋯S hydrogen bonding links adjacent mol­ecules to form a centrosymmetric supra­molecular dimer. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961347/ /pubmed/21202539 http://dx.doi.org/10.1107/S1600536808012944 Text en © Shan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shan, Shang
Tian, Yu-Liang
Wang, Shan-Heng
Wang, Wen-Long
Xu, Ying-Li
Benzyl 3-[(E)-benzyl­idene]dithio­carbazate
title Benzyl 3-[(E)-benzyl­idene]dithio­carbazate
title_full Benzyl 3-[(E)-benzyl­idene]dithio­carbazate
title_fullStr Benzyl 3-[(E)-benzyl­idene]dithio­carbazate
title_full_unstemmed Benzyl 3-[(E)-benzyl­idene]dithio­carbazate
title_short Benzyl 3-[(E)-benzyl­idene]dithio­carbazate
title_sort benzyl 3-[(e)-benzyl­idene]dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961347/
https://www.ncbi.nlm.nih.gov/pubmed/21202539
http://dx.doi.org/10.1107/S1600536808012944
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AT wangshanheng benzyl3ebenzylidenedithiocarbazate
AT wangwenlong benzyl3ebenzylidenedithiocarbazate
AT xuyingli benzyl3ebenzylidenedithiocarbazate

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