Bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(IV)

The Sn(IV) atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(3)(CH(3))(2)Cl], lies on a center of inversion in a tetra­gonally compressed octa­hedron; two independent Br atoms share the same site as two independent chlorine atoms so that the anion effectively has one Cl and three Br atoms. The occupan...

Descripción completa

Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961353/
https://www.ncbi.nlm.nih.gov/pubmed/21202515
http://dx.doi.org/10.1107/S1600536808014669
Descripción
Sumario:The Sn(IV) atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(3)(CH(3))(2)Cl], lies on a center of inversion in a tetra­gonally compressed octa­hedron; two independent Br atoms share the same site as two independent chlorine atoms so that the anion effectively has one Cl and three Br atoms. The occupancies of the Br atoms are 0.721 (1) and 0.779 (1), and those of the Cl atoms are 0.279 (1) and 0.221 (1). The crystal structure involves N—H⋯halogen hydrogen bonds.

Ejemplares similares