Bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(IV)

The Sn(IV) atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(3)(CH(3))(2)Cl], lies on a center of inversion in a tetra­gonally compressed octa­hedron; two independent Br atoms share the same site as two independent chlorine atoms so that the anion effectively has one Cl and three Br atoms. The occupan...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961353/
https://www.ncbi.nlm.nih.gov/pubmed/21202515
http://dx.doi.org/10.1107/S1600536808014669
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author Lo, Kong Mun
Ng, Seik Weng
author_facet Lo, Kong Mun
Ng, Seik Weng
author_sort Lo, Kong Mun
collection PubMed
description The Sn(IV) atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(3)(CH(3))(2)Cl], lies on a center of inversion in a tetra­gonally compressed octa­hedron; two independent Br atoms share the same site as two independent chlorine atoms so that the anion effectively has one Cl and three Br atoms. The occupancies of the Br atoms are 0.721 (1) and 0.779 (1), and those of the Cl atoms are 0.279 (1) and 0.221 (1). The crystal structure involves N—H⋯halogen hydrogen bonds.
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spelling pubmed-29613532010-12-30 Bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(IV) Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(3)(CH(3))(2)Cl], lies on a center of inversion in a tetra­gonally compressed octa­hedron; two independent Br atoms share the same site as two independent chlorine atoms so that the anion effectively has one Cl and three Br atoms. The occupancies of the Br atoms are 0.721 (1) and 0.779 (1), and those of the Cl atoms are 0.279 (1) and 0.221 (1). The crystal structure involves N—H⋯halogen hydrogen bonds. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961353/ /pubmed/21202515 http://dx.doi.org/10.1107/S1600536808014669 Text en © Lo and Ng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lo, Kong Mun
Ng, Seik Weng
Bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(IV)
title Bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(IV)
title_full Bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(IV)
title_fullStr Bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(IV)
title_full_unstemmed Bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(IV)
title_short Bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(IV)
title_sort bis[4-(dimethyl­amino)pyridinium] tribromidochloridodimethyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961353/
https://www.ncbi.nlm.nih.gov/pubmed/21202515
http://dx.doi.org/10.1107/S1600536808014669
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AT ngseikweng bis4dimethylaminopyridiniumtribromidochloridodimethylstannateiv

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