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2,4,6,7-Tetramethyl-3-phenylsulfinyl-1-benzofuran
In the title compound, C(18)H(18)O(2)S, the O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the planar benzofuran fragment. The phenyl ring is nearly perpendicular to the benzofuran system [88.56 (7)°] and is tilted slightly towards it. Molecules form pseudo-h...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961357/ https://www.ncbi.nlm.nih.gov/pubmed/21202652 http://dx.doi.org/10.1107/S1600536808015031 |
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author | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_facet | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_sort | Choi, Hong Dae |
collection | PubMed |
description | In the title compound, C(18)H(18)O(2)S, the O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the planar benzofuran fragment. The phenyl ring is nearly perpendicular to the benzofuran system [88.56 (7)°] and is tilted slightly towards it. Molecules form pseudo-helices along the a axis. The crystal structure is stabilized by a C—H⋯π interaction between a methyl H atom and the phenyl ring of the phenylsulfinyl substituent, and by intra- and intermolecular C—H⋯O interactions. |
format | Text |
id | pubmed-2961357 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613572010-12-30 2,4,6,7-Tetramethyl-3-phenylsulfinyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(18)O(2)S, the O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the planar benzofuran fragment. The phenyl ring is nearly perpendicular to the benzofuran system [88.56 (7)°] and is tilted slightly towards it. Molecules form pseudo-helices along the a axis. The crystal structure is stabilized by a C—H⋯π interaction between a methyl H atom and the phenyl ring of the phenylsulfinyl substituent, and by intra- and intermolecular C—H⋯O interactions. International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961357/ /pubmed/21202652 http://dx.doi.org/10.1107/S1600536808015031 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk 2,4,6,7-Tetramethyl-3-phenylsulfinyl-1-benzofuran |
title | 2,4,6,7-Tetramethyl-3-phenylsulfinyl-1-benzofuran |
title_full | 2,4,6,7-Tetramethyl-3-phenylsulfinyl-1-benzofuran |
title_fullStr | 2,4,6,7-Tetramethyl-3-phenylsulfinyl-1-benzofuran |
title_full_unstemmed | 2,4,6,7-Tetramethyl-3-phenylsulfinyl-1-benzofuran |
title_short | 2,4,6,7-Tetramethyl-3-phenylsulfinyl-1-benzofuran |
title_sort | 2,4,6,7-tetramethyl-3-phenylsulfinyl-1-benzofuran |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961357/ https://www.ncbi.nlm.nih.gov/pubmed/21202652 http://dx.doi.org/10.1107/S1600536808015031 |
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