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2,4,6,7-Tetra­methyl-3-phenyl­sulfinyl-1-benzofuran

In the title compound, C(18)H(18)O(2)S, the O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the planar benzofuran fragment. The phenyl ring is nearly perpendicular to the benzofuran system [88.56 (7)°] and is tilted slightly towards it. Molecules form pseudo-h...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961357/
https://www.ncbi.nlm.nih.gov/pubmed/21202652
http://dx.doi.org/10.1107/S1600536808015031
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author Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(18)H(18)O(2)S, the O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the planar benzofuran fragment. The phenyl ring is nearly perpendicular to the benzofuran system [88.56 (7)°] and is tilted slightly towards it. Molecules form pseudo-helices along the a axis. The crystal structure is stabilized by a C—H⋯π inter­action between a methyl H atom and the phenyl ring of the phenyl­sulfinyl substituent, and by intra- and inter­molecular C—H⋯O inter­actions.
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spelling pubmed-29613572010-12-30 2,4,6,7-Tetra­methyl-3-phenyl­sulfinyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(18)O(2)S, the O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the planar benzofuran fragment. The phenyl ring is nearly perpendicular to the benzofuran system [88.56 (7)°] and is tilted slightly towards it. Molecules form pseudo-helices along the a axis. The crystal structure is stabilized by a C—H⋯π inter­action between a methyl H atom and the phenyl ring of the phenyl­sulfinyl substituent, and by intra- and inter­molecular C—H⋯O inter­actions. International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961357/ /pubmed/21202652 http://dx.doi.org/10.1107/S1600536808015031 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
2,4,6,7-Tetra­methyl-3-phenyl­sulfinyl-1-benzofuran
title 2,4,6,7-Tetra­methyl-3-phenyl­sulfinyl-1-benzofuran
title_full 2,4,6,7-Tetra­methyl-3-phenyl­sulfinyl-1-benzofuran
title_fullStr 2,4,6,7-Tetra­methyl-3-phenyl­sulfinyl-1-benzofuran
title_full_unstemmed 2,4,6,7-Tetra­methyl-3-phenyl­sulfinyl-1-benzofuran
title_short 2,4,6,7-Tetra­methyl-3-phenyl­sulfinyl-1-benzofuran
title_sort 2,4,6,7-tetra­methyl-3-phenyl­sulfinyl-1-benzofuran
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961357/
https://www.ncbi.nlm.nih.gov/pubmed/21202652
http://dx.doi.org/10.1107/S1600536808015031
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