5-Iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran

The title compound, C(16)H(13)IO(2)S, was prepared by the oxidation of 5-iodo-7-methyl-3-methyl­sulfanyl-2-phenyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The phenyl ring makes a dihedral angle of 27.17 (9)° with the plane of the benzofuran fragment, with the O atom and the methyl group of th...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Kim, Byung Ki, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961360/
https://www.ncbi.nlm.nih.gov/pubmed/21202627
http://dx.doi.org/10.1107/S1600536808014694
Descripción
Sumario:The title compound, C(16)H(13)IO(2)S, was prepared by the oxidation of 5-iodo-7-methyl-3-methyl­sulfanyl-2-phenyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The phenyl ring makes a dihedral angle of 27.17 (9)° with the plane of the benzofuran fragment, with the O atom and the methyl group of the methyl­sulfinyl substituent lying on opposite sides of this plane. The crystal structure exhibits inter­molecular C—H⋯I inter­actions, and an I⋯O halogen bond of 3.107 (2) Å with a nearly linear C—I⋯O angle of 173.73 (6)°.

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