5-Iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran

The title compound, C(16)H(13)IO(2)S, was prepared by the oxidation of 5-iodo-7-methyl-3-methyl­sulfanyl-2-phenyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The phenyl ring makes a dihedral angle of 27.17 (9)° with the plane of the benzofuran fragment, with the O atom and the methyl group of th...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Kim, Byung Ki, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961360/
https://www.ncbi.nlm.nih.gov/pubmed/21202627
http://dx.doi.org/10.1107/S1600536808014694
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author Choi, Hong Dae
Seo, Pil Ja
Kim, Byung Ki
Son, Byeng Wha
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Kim, Byung Ki
Son, Byeng Wha
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description The title compound, C(16)H(13)IO(2)S, was prepared by the oxidation of 5-iodo-7-methyl-3-methyl­sulfanyl-2-phenyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The phenyl ring makes a dihedral angle of 27.17 (9)° with the plane of the benzofuran fragment, with the O atom and the methyl group of the methyl­sulfinyl substituent lying on opposite sides of this plane. The crystal structure exhibits inter­molecular C—H⋯I inter­actions, and an I⋯O halogen bond of 3.107 (2) Å with a nearly linear C—I⋯O angle of 173.73 (6)°.
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spelling pubmed-29613602010-12-30 5-Iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Kim, Byung Ki Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(13)IO(2)S, was prepared by the oxidation of 5-iodo-7-methyl-3-methyl­sulfanyl-2-phenyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The phenyl ring makes a dihedral angle of 27.17 (9)° with the plane of the benzofuran fragment, with the O atom and the methyl group of the methyl­sulfinyl substituent lying on opposite sides of this plane. The crystal structure exhibits inter­molecular C—H⋯I inter­actions, and an I⋯O halogen bond of 3.107 (2) Å with a nearly linear C—I⋯O angle of 173.73 (6)°. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961360/ /pubmed/21202627 http://dx.doi.org/10.1107/S1600536808014694 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Kim, Byung Ki
Son, Byeng Wha
Lee, Uk
5-Iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran
title 5-Iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran
title_full 5-Iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran
title_fullStr 5-Iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran
title_full_unstemmed 5-Iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran
title_short 5-Iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran
title_sort 5-iodo-7-methyl-3-methyl­sulfinyl-2-phenyl-1-benzofuran
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961360/
https://www.ncbi.nlm.nih.gov/pubmed/21202627
http://dx.doi.org/10.1107/S1600536808014694
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AT sonbyengwha 5iodo7methyl3methylsulfinyl2phenyl1benzofuran
AT leeuk 5iodo7methyl3methylsulfinyl2phenyl1benzofuran

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