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Di-μ-acetato-μ-aqua-bis­[acetatobis(1H-benzimidazole)cobalt(II)]

In the title compound, [Co(2)(C(2)H(3)O(2))(4)(C(7)H(6)N(2))(4)(H(2)O)], the half-mol­ecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full mol­ecule. The Co(II) ions are approximately octahedrally coordinated with a cis-N(2)O(4) coordination sphere....

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Detalles Bibliográficos
Autores principales: Zimmermann, Iwan, Keene, Tony D., Neels, Antonia, Decurtins, Silvio
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961362/
https://www.ncbi.nlm.nih.gov/pubmed/21202524
http://dx.doi.org/10.1107/S1600536808015596
Descripción
Sumario:In the title compound, [Co(2)(C(2)H(3)O(2))(4)(C(7)H(6)N(2))(4)(H(2)O)], the half-mol­ecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full mol­ecule. The Co(II) ions are approximately octahedrally coordinated with a cis-N(2)O(4) coordination sphere. The compound features intra­molecular O—H⋯O hydrogen bonds between the non-bridging acetate groups and the bridging water mol­ecule, and inter­molecular N—H⋯O hydrogen bonds between the acetates and amine H atoms of the benzimidazoles which determine the mol­ecular packing in the crystal structure.