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Di-μ-acetato-μ-aqua-bis[acetatobis(1H-benzimidazole)cobalt(II)]
In the title compound, [Co(2)(C(2)H(3)O(2))(4)(C(7)H(6)N(2))(4)(H(2)O)], the half-molecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full molecule. The Co(II) ions are approximately octahedrally coordinated with a cis-N(2)O(4) coordination sphere....
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961362/ https://www.ncbi.nlm.nih.gov/pubmed/21202524 http://dx.doi.org/10.1107/S1600536808015596 |
Sumario: | In the title compound, [Co(2)(C(2)H(3)O(2))(4)(C(7)H(6)N(2))(4)(H(2)O)], the half-molecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full molecule. The Co(II) ions are approximately octahedrally coordinated with a cis-N(2)O(4) coordination sphere. The compound features intramolecular O—H⋯O hydrogen bonds between the non-bridging acetate groups and the bridging water molecule, and intermolecular N—H⋯O hydrogen bonds between the acetates and amine H atoms of the benzimidazoles which determine the molecular packing in the crystal structure. |
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