Di-μ-acetato-μ-aqua-bis­[acetatobis(1H-benzimidazole)cobalt(II)]

In the title compound, [Co(2)(C(2)H(3)O(2))(4)(C(7)H(6)N(2))(4)(H(2)O)], the half-mol­ecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full mol­ecule. The Co(II) ions are approximately octahedrally coordinated with a cis-N(2)O(4) coordination sphere....

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Detalles Bibliográficos
Autores principales: Zimmermann, Iwan, Keene, Tony D., Neels, Antonia, Decurtins, Silvio
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961362/
https://www.ncbi.nlm.nih.gov/pubmed/21202524
http://dx.doi.org/10.1107/S1600536808015596
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author Zimmermann, Iwan
Keene, Tony D.
Neels, Antonia
Decurtins, Silvio
author_facet Zimmermann, Iwan
Keene, Tony D.
Neels, Antonia
Decurtins, Silvio
author_sort Zimmermann, Iwan
collection PubMed
description In the title compound, [Co(2)(C(2)H(3)O(2))(4)(C(7)H(6)N(2))(4)(H(2)O)], the half-mol­ecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full mol­ecule. The Co(II) ions are approximately octahedrally coordinated with a cis-N(2)O(4) coordination sphere. The compound features intra­molecular O—H⋯O hydrogen bonds between the non-bridging acetate groups and the bridging water mol­ecule, and inter­molecular N—H⋯O hydrogen bonds between the acetates and amine H atoms of the benzimidazoles which determine the mol­ecular packing in the crystal structure.
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spelling pubmed-29613622010-12-30 Di-μ-acetato-μ-aqua-bis­[acetatobis(1H-benzimidazole)cobalt(II)] Zimmermann, Iwan Keene, Tony D. Neels, Antonia Decurtins, Silvio Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(2)(C(2)H(3)O(2))(4)(C(7)H(6)N(2))(4)(H(2)O)], the half-mol­ecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full mol­ecule. The Co(II) ions are approximately octahedrally coordinated with a cis-N(2)O(4) coordination sphere. The compound features intra­molecular O—H⋯O hydrogen bonds between the non-bridging acetate groups and the bridging water mol­ecule, and inter­molecular N—H⋯O hydrogen bonds between the acetates and amine H atoms of the benzimidazoles which determine the mol­ecular packing in the crystal structure. International Union of Crystallography 2008-05-30 /pmc/articles/PMC2961362/ /pubmed/21202524 http://dx.doi.org/10.1107/S1600536808015596 Text en © Zimmermann et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zimmermann, Iwan
Keene, Tony D.
Neels, Antonia
Decurtins, Silvio
Di-μ-acetato-μ-aqua-bis­[acetatobis(1H-benzimidazole)cobalt(II)]
title Di-μ-acetato-μ-aqua-bis­[acetatobis(1H-benzimidazole)cobalt(II)]
title_full Di-μ-acetato-μ-aqua-bis­[acetatobis(1H-benzimidazole)cobalt(II)]
title_fullStr Di-μ-acetato-μ-aqua-bis­[acetatobis(1H-benzimidazole)cobalt(II)]
title_full_unstemmed Di-μ-acetato-μ-aqua-bis­[acetatobis(1H-benzimidazole)cobalt(II)]
title_short Di-μ-acetato-μ-aqua-bis­[acetatobis(1H-benzimidazole)cobalt(II)]
title_sort di-μ-acetato-μ-aqua-bis­[acetatobis(1h-benzimidazole)cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961362/
https://www.ncbi.nlm.nih.gov/pubmed/21202524
http://dx.doi.org/10.1107/S1600536808015596
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AT neelsantonia dimacetatomaquabisacetatobis1hbenzimidazolecobaltii
AT decurtinssilvio dimacetatomaquabisacetatobis1hbenzimidazolecobaltii

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