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{μ-6,6′-Diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(III)nickel(II)
In the title heteronuclear Ni(II)–Ho(III) complex (systematic name: {μ-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (1),O (1′),O (6),O (6′):2κ(4) O (1),N,N′,O (1′)}trinitrato-1κ(6) O,O′-holmium(III)nickel(II)), [HoNi(C(20)H(22)N(2)O(4))(NO(3))(3)], with the hexa...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961363/ https://www.ncbi.nlm.nih.gov/pubmed/21202492 http://dx.doi.org/10.1107/S1600536808013755 |
Sumario: | In the title heteronuclear Ni(II)–Ho(III) complex (systematic name: {μ-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (1),O (1′),O (6),O (6′):2κ(4) O (1),N,N′,O (1′)}trinitrato-1κ(6) O,O′-holmium(III)nickel(II)), [HoNi(C(20)H(22)N(2)O(4))(NO(3))(3)], with the hexadentate Schiff base compartmental ligand N,N′-bis(3-ethoxysalicylidene)ethylenediamine (H(2) L), the Ho and Ni atoms are doubly bridged by two phenolate O atoms of the Schiff base ligand. The coordination of Ni is square-planar with the donor centers of two imine N atoms and two phenolate O atoms. The holmium(III) center has a tenfold coordination environment of O atoms, involving the phenolate O atoms, two ethoxy O atoms and two O atoms each from the three nitrates. Weak C—H⋯O and O⋯Ni [3.383 (4) Å] interactions generate a two-dimensional zigzag sheet. |
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