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{μ-6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratoholmium(III)nickel(II)

In the title heteronuclear Ni(II)–Ho(III) complex (systematic name: {μ-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-1κ(4) O (1),O (1′),O (6),O (6′):2κ(4) O (1),N,N′,O (1′)}trinitrato-1κ(6) O,O′-holmium(III)nickel(II)), [HoNi(C(20)H(22)N(2)O(4))(NO(3))(3)], with the hexa­...

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Autores principales: Xiao, Yi-An, Fu, Xiang-Kai, Sui, Yan, Wu, Qing, Xiong, Shao-Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961363/
https://www.ncbi.nlm.nih.gov/pubmed/21202492
http://dx.doi.org/10.1107/S1600536808013755
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author Xiao, Yi-An
Fu, Xiang-Kai
Sui, Yan
Wu, Qing
Xiong, Shao-Hui
author_facet Xiao, Yi-An
Fu, Xiang-Kai
Sui, Yan
Wu, Qing
Xiong, Shao-Hui
author_sort Xiao, Yi-An
collection PubMed
description In the title heteronuclear Ni(II)–Ho(III) complex (systematic name: {μ-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-1κ(4) O (1),O (1′),O (6),O (6′):2κ(4) O (1),N,N′,O (1′)}trinitrato-1κ(6) O,O′-holmium(III)nickel(II)), [HoNi(C(20)H(22)N(2)O(4))(NO(3))(3)], with the hexa­dentate Schiff base compartmental ligand N,N′-bis­(3-ethoxy­salicyl­idene)ethyl­enediamine (H(2) L), the Ho and Ni atoms are doubly bridged by two phenolate O atoms of the Schiff base ligand. The coordination of Ni is square-planar with the donor centers of two imine N atoms and two phenolate O atoms. The holmium(III) center has a tenfold ­coordination environment of O atoms, involving the phenolate O atoms, two eth­oxy O atoms and two O atoms each from the three nitrates. Weak C—H⋯O and O⋯Ni [3.383 (4) Å] inter­actions generate a two-dimensional zigzag sheet.
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spelling pubmed-29613632010-12-30 {μ-6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratoholmium(III)nickel(II) Xiao, Yi-An Fu, Xiang-Kai Sui, Yan Wu, Qing Xiong, Shao-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title heteronuclear Ni(II)–Ho(III) complex (systematic name: {μ-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-1κ(4) O (1),O (1′),O (6),O (6′):2κ(4) O (1),N,N′,O (1′)}trinitrato-1κ(6) O,O′-holmium(III)nickel(II)), [HoNi(C(20)H(22)N(2)O(4))(NO(3))(3)], with the hexa­dentate Schiff base compartmental ligand N,N′-bis­(3-ethoxy­salicyl­idene)ethyl­enediamine (H(2) L), the Ho and Ni atoms are doubly bridged by two phenolate O atoms of the Schiff base ligand. The coordination of Ni is square-planar with the donor centers of two imine N atoms and two phenolate O atoms. The holmium(III) center has a tenfold ­coordination environment of O atoms, involving the phenolate O atoms, two eth­oxy O atoms and two O atoms each from the three nitrates. Weak C—H⋯O and O⋯Ni [3.383 (4) Å] inter­actions generate a two-dimensional zigzag sheet. International Union of Crystallography 2008-05-14 /pmc/articles/PMC2961363/ /pubmed/21202492 http://dx.doi.org/10.1107/S1600536808013755 Text en © Xiao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xiao, Yi-An
Fu, Xiang-Kai
Sui, Yan
Wu, Qing
Xiong, Shao-Hui
{μ-6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratoholmium(III)nickel(II)
title {μ-6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratoholmium(III)nickel(II)
title_full {μ-6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratoholmium(III)nickel(II)
title_fullStr {μ-6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratoholmium(III)nickel(II)
title_full_unstemmed {μ-6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratoholmium(III)nickel(II)
title_short {μ-6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratoholmium(III)nickel(II)
title_sort {μ-6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratoholmium(iii)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961363/
https://www.ncbi.nlm.nih.gov/pubmed/21202492
http://dx.doi.org/10.1107/S1600536808013755
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