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{μ-6,6′-Diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(III)nickel(II)
In the title heteronuclear Ni(II)–Ho(III) complex (systematic name: {μ-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (1),O (1′),O (6),O (6′):2κ(4) O (1),N,N′,O (1′)}trinitrato-1κ(6) O,O′-holmium(III)nickel(II)), [HoNi(C(20)H(22)N(2)O(4))(NO(3))(3)], with the hexa...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961363/ https://www.ncbi.nlm.nih.gov/pubmed/21202492 http://dx.doi.org/10.1107/S1600536808013755 |
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author | Xiao, Yi-An Fu, Xiang-Kai Sui, Yan Wu, Qing Xiong, Shao-Hui |
author_facet | Xiao, Yi-An Fu, Xiang-Kai Sui, Yan Wu, Qing Xiong, Shao-Hui |
author_sort | Xiao, Yi-An |
collection | PubMed |
description | In the title heteronuclear Ni(II)–Ho(III) complex (systematic name: {μ-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (1),O (1′),O (6),O (6′):2κ(4) O (1),N,N′,O (1′)}trinitrato-1κ(6) O,O′-holmium(III)nickel(II)), [HoNi(C(20)H(22)N(2)O(4))(NO(3))(3)], with the hexadentate Schiff base compartmental ligand N,N′-bis(3-ethoxysalicylidene)ethylenediamine (H(2) L), the Ho and Ni atoms are doubly bridged by two phenolate O atoms of the Schiff base ligand. The coordination of Ni is square-planar with the donor centers of two imine N atoms and two phenolate O atoms. The holmium(III) center has a tenfold coordination environment of O atoms, involving the phenolate O atoms, two ethoxy O atoms and two O atoms each from the three nitrates. Weak C—H⋯O and O⋯Ni [3.383 (4) Å] interactions generate a two-dimensional zigzag sheet. |
format | Text |
id | pubmed-2961363 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613632010-12-30 {μ-6,6′-Diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(III)nickel(II) Xiao, Yi-An Fu, Xiang-Kai Sui, Yan Wu, Qing Xiong, Shao-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title heteronuclear Ni(II)–Ho(III) complex (systematic name: {μ-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (1),O (1′),O (6),O (6′):2κ(4) O (1),N,N′,O (1′)}trinitrato-1κ(6) O,O′-holmium(III)nickel(II)), [HoNi(C(20)H(22)N(2)O(4))(NO(3))(3)], with the hexadentate Schiff base compartmental ligand N,N′-bis(3-ethoxysalicylidene)ethylenediamine (H(2) L), the Ho and Ni atoms are doubly bridged by two phenolate O atoms of the Schiff base ligand. The coordination of Ni is square-planar with the donor centers of two imine N atoms and two phenolate O atoms. The holmium(III) center has a tenfold coordination environment of O atoms, involving the phenolate O atoms, two ethoxy O atoms and two O atoms each from the three nitrates. Weak C—H⋯O and O⋯Ni [3.383 (4) Å] interactions generate a two-dimensional zigzag sheet. International Union of Crystallography 2008-05-14 /pmc/articles/PMC2961363/ /pubmed/21202492 http://dx.doi.org/10.1107/S1600536808013755 Text en © Xiao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xiao, Yi-An Fu, Xiang-Kai Sui, Yan Wu, Qing Xiong, Shao-Hui {μ-6,6′-Diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(III)nickel(II) |
title | {μ-6,6′-Diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(III)nickel(II) |
title_full | {μ-6,6′-Diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(III)nickel(II) |
title_fullStr | {μ-6,6′-Diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(III)nickel(II) |
title_full_unstemmed | {μ-6,6′-Diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(III)nickel(II) |
title_short | {μ-6,6′-Diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(III)nickel(II) |
title_sort | {μ-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratoholmium(iii)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961363/ https://www.ncbi.nlm.nih.gov/pubmed/21202492 http://dx.doi.org/10.1107/S1600536808013755 |
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