catena-Poly[[diaqua­manganese(II)]-di-μ-pyridine-3-sulfonato-κ(2) N:O;κ(2) O:N]

In the title polymeric complex, [Mn(C(5)H(4)NO(3)S)(2)(H(2)O)(2)](n), the Mn atom is located on a centre of inversion and is coordinated by two O atoms and two N atoms derived from four different pyridine-3-sulfonate (pySO(3)) ligands, and two O atoms derived from two water mol­ecules in a distorted...

Descripción completa

Detalles Bibliográficos
Autores principales: Qiu, Zhi-Hui, Liang, Fu-Pei, Ruan, Qing-Feng, Zhao, Shan-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961366/
https://www.ncbi.nlm.nih.gov/pubmed/21202458
http://dx.doi.org/10.1107/S1600536808012282
Descripción
Sumario:In the title polymeric complex, [Mn(C(5)H(4)NO(3)S)(2)(H(2)O)(2)](n), the Mn atom is located on a centre of inversion and is coordinated by two O atoms and two N atoms derived from four different pyridine-3-sulfonate (pySO(3)) ligands, and two O atoms derived from two water mol­ecules in a distorted trans-N(2)O(4) octa­hedral geometry. The metal atoms are bridged by the pySO(3) ligands to form a one-dimensional chain. The chains are further connected into a three-dimensional architecture via hydrogen bonds.

Ejemplares similares