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{2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}oxidovanadium(IV)
The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N′-bis(salicylidene)ethylenediamine under hydrothermal conditions. The asymmetric unit contains two molecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961374/ https://www.ncbi.nlm.nih.gov/pubmed/21202467 http://dx.doi.org/10.1107/S1600536808010611 |
| _version_ | 1782188967357054976 |
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| author | Wang, Cheng Yuan, Ji-Hong Xie, Gang Yu, Ming-Juan Li, Jing |
| author_facet | Wang, Cheng Yuan, Ji-Hong Xie, Gang Yu, Ming-Juan Li, Jing |
| author_sort | Wang, Cheng |
| collection | PubMed |
| description | The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N′-bis(salicylidene)ethylenediamine under hydrothermal conditions. The asymmetric unit contains two molecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position. Weak C—H⋯O hydrogen bonds lead to a three-dimensional supramolecular structure. |
| format | Text |
| id | pubmed-2961374 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29613742010-12-30 {2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}oxidovanadium(IV) Wang, Cheng Yuan, Ji-Hong Xie, Gang Yu, Ming-Juan Li, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N′-bis(salicylidene)ethylenediamine under hydrothermal conditions. The asymmetric unit contains two molecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position. Weak C—H⋯O hydrogen bonds lead to a three-dimensional supramolecular structure. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961374/ /pubmed/21202467 http://dx.doi.org/10.1107/S1600536808010611 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Cheng Yuan, Ji-Hong Xie, Gang Yu, Ming-Juan Li, Jing {2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}oxidovanadium(IV) |
| title | {2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}oxidovanadium(IV) |
| title_full | {2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}oxidovanadium(IV) |
| title_fullStr | {2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}oxidovanadium(IV) |
| title_full_unstemmed | {2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}oxidovanadium(IV) |
| title_short | {2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}oxidovanadium(IV) |
| title_sort | {2,2′-[ethylenebis(nitrilomethylidyne)]diphenolato-κ(4)
o,n,n′,o′}oxidovanadium(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961374/ https://www.ncbi.nlm.nih.gov/pubmed/21202467 http://dx.doi.org/10.1107/S1600536808010611 |
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