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(S)-2-(Pyrrolidinium-2-ylmethylsulfanyl)pyridinium dibromide
In the title compound, C(10)H(16)N(2)S(2+)·2Br(−), the pyrrolidine ring displays an envelope conformation, with the flap C atom lying 0.484 (5) Å out of the plane of the rest of the pyrrolidine ring. The thioether group connects the pyridine ring and the 2-methylpyrrolidine group. Both pyrrolidine...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961376/ https://www.ncbi.nlm.nih.gov/pubmed/21202651 http://dx.doi.org/10.1107/S1600536808008313 |
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author | Zhang, Shuai Wang, Yifeng Xia, Aibao Luo, Shuping |
author_facet | Zhang, Shuai Wang, Yifeng Xia, Aibao Luo, Shuping |
author_sort | Zhang, Shuai |
collection | PubMed |
description | In the title compound, C(10)H(16)N(2)S(2+)·2Br(−), the pyrrolidine ring displays an envelope conformation, with the flap C atom lying 0.484 (5) Å out of the plane of the rest of the pyrrolidine ring. The thioether group connects the pyridine ring and the 2-methylpyrrolidine group. Both pyrrolidine NH bonds form hydrogen bonds to the bromide anions. These hydrogen bonds link the cations and anions in a helical chain along the c axis. |
format | Text |
id | pubmed-2961376 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613762010-12-30 (S)-2-(Pyrrolidinium-2-ylmethylsulfanyl)pyridinium dibromide Zhang, Shuai Wang, Yifeng Xia, Aibao Luo, Shuping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(16)N(2)S(2+)·2Br(−), the pyrrolidine ring displays an envelope conformation, with the flap C atom lying 0.484 (5) Å out of the plane of the rest of the pyrrolidine ring. The thioether group connects the pyridine ring and the 2-methylpyrrolidine group. Both pyrrolidine NH bonds form hydrogen bonds to the bromide anions. These hydrogen bonds link the cations and anions in a helical chain along the c axis. International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961376/ /pubmed/21202651 http://dx.doi.org/10.1107/S1600536808008313 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Shuai Wang, Yifeng Xia, Aibao Luo, Shuping (S)-2-(Pyrrolidinium-2-ylmethylsulfanyl)pyridinium dibromide |
title | (S)-2-(Pyrrolidinium-2-ylmethylsulfanyl)pyridinium dibromide |
title_full | (S)-2-(Pyrrolidinium-2-ylmethylsulfanyl)pyridinium dibromide |
title_fullStr | (S)-2-(Pyrrolidinium-2-ylmethylsulfanyl)pyridinium dibromide |
title_full_unstemmed | (S)-2-(Pyrrolidinium-2-ylmethylsulfanyl)pyridinium dibromide |
title_short | (S)-2-(Pyrrolidinium-2-ylmethylsulfanyl)pyridinium dibromide |
title_sort | (s)-2-(pyrrolidinium-2-ylmethylsulfanyl)pyridinium dibromide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961376/ https://www.ncbi.nlm.nih.gov/pubmed/21202651 http://dx.doi.org/10.1107/S1600536808008313 |
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