(S)-2-(Pyrrolidinium-2-ylmethyl­sulfan­yl)pyridinium dibromide

In the title compound, C(10)H(16)N(2)S(2+)·2Br(−), the pyrrolidine ring displays an envelope conformation, with the flap C atom lying 0.484 (5) Å out of the plane of the rest of the pyrrolidine ring. The thio­ether group connects the pyridine ring and the 2-methyl­pyrrolidine group. Both pyrrolidine...

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Detalles Bibliográficos
Autores principales: Zhang, Shuai, Wang, Yifeng, Xia, Aibao, Luo, Shuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961376/
https://www.ncbi.nlm.nih.gov/pubmed/21202651
http://dx.doi.org/10.1107/S1600536808008313
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author Zhang, Shuai
Wang, Yifeng
Xia, Aibao
Luo, Shuping
author_facet Zhang, Shuai
Wang, Yifeng
Xia, Aibao
Luo, Shuping
author_sort Zhang, Shuai
collection PubMed
description In the title compound, C(10)H(16)N(2)S(2+)·2Br(−), the pyrrolidine ring displays an envelope conformation, with the flap C atom lying 0.484 (5) Å out of the plane of the rest of the pyrrolidine ring. The thio­ether group connects the pyridine ring and the 2-methyl­pyrrolidine group. Both pyrrolidine NH bonds form hydrogen bonds to the bromide anions. These hydrogen bonds link the cations and anions in a helical chain along the c axis.
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spelling pubmed-29613762010-12-30 (S)-2-(Pyrrolidinium-2-ylmethyl­sulfan­yl)pyridinium dibromide Zhang, Shuai Wang, Yifeng Xia, Aibao Luo, Shuping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(16)N(2)S(2+)·2Br(−), the pyrrolidine ring displays an envelope conformation, with the flap C atom lying 0.484 (5) Å out of the plane of the rest of the pyrrolidine ring. The thio­ether group connects the pyridine ring and the 2-methyl­pyrrolidine group. Both pyrrolidine NH bonds form hydrogen bonds to the bromide anions. These hydrogen bonds link the cations and anions in a helical chain along the c axis. International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961376/ /pubmed/21202651 http://dx.doi.org/10.1107/S1600536808008313 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Shuai
Wang, Yifeng
Xia, Aibao
Luo, Shuping
(S)-2-(Pyrrolidinium-2-ylmethyl­sulfan­yl)pyridinium dibromide
title (S)-2-(Pyrrolidinium-2-ylmethyl­sulfan­yl)pyridinium dibromide
title_full (S)-2-(Pyrrolidinium-2-ylmethyl­sulfan­yl)pyridinium dibromide
title_fullStr (S)-2-(Pyrrolidinium-2-ylmethyl­sulfan­yl)pyridinium dibromide
title_full_unstemmed (S)-2-(Pyrrolidinium-2-ylmethyl­sulfan­yl)pyridinium dibromide
title_short (S)-2-(Pyrrolidinium-2-ylmethyl­sulfan­yl)pyridinium dibromide
title_sort (s)-2-(pyrrolidinium-2-ylmethyl­sulfan­yl)pyridinium dibromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961376/
https://www.ncbi.nlm.nih.gov/pubmed/21202651
http://dx.doi.org/10.1107/S1600536808008313
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AT xiaaibao s2pyrrolidinium2ylmethylsulfanylpyridiniumdibromide
AT luoshuping s2pyrrolidinium2ylmethylsulfanylpyridiniumdibromide

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