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Poly[diaqua­bis(μ(2)-azido-κ(2) N (1):N (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)]

In the title compound, [Cd(2)(C(6)H(4)NO(3))(2)(N(3))(2)(H(2)O)(2)](n), one Cd(II) atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octa­hedral geometry. The o...

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Detalles Bibliográficos
Autores principales: Wang, Zhi-Xiang, Li, Xiu-Bing, Sun, Bai-Wang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961384/
https://www.ncbi.nlm.nih.gov/pubmed/21202481
http://dx.doi.org/10.1107/S1600536808013196
Descripción
Sumario:In the title compound, [Cd(2)(C(6)H(4)NO(3))(2)(N(3))(2)(H(2)O)(2)](n), one Cd(II) atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octa­hedral geometry. The other Cd(II) atom, also lying on an inversion center, is coordinated by four O atoms from two bridging 1-oxoisonicotinate ligands and two water mol­ecules and two N atoms of two bridging azide ligands in a slightly distorted octa­hedral geometry. The Cd atoms are connected via the 1-oxoisonicotinate and azide ligands into a two-dimensional coordination network. The crystal structure involves O—H⋯N and O—H⋯O hydrogen bonds.