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Poly[diaquabis(μ(2)-azido-κ(2) N (1):N (1))bis(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)]
In the title compound, [Cd(2)(C(6)H(4)NO(3))(2)(N(3))(2)(H(2)O)(2)](n), one Cd(II) atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octahedral geometry. The o...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961384/ https://www.ncbi.nlm.nih.gov/pubmed/21202481 http://dx.doi.org/10.1107/S1600536808013196 |
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author | Wang, Zhi-Xiang Li, Xiu-Bing Sun, Bai-Wang |
author_facet | Wang, Zhi-Xiang Li, Xiu-Bing Sun, Bai-Wang |
author_sort | Wang, Zhi-Xiang |
collection | PubMed |
description | In the title compound, [Cd(2)(C(6)H(4)NO(3))(2)(N(3))(2)(H(2)O)(2)](n), one Cd(II) atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octahedral geometry. The other Cd(II) atom, also lying on an inversion center, is coordinated by four O atoms from two bridging 1-oxoisonicotinate ligands and two water molecules and two N atoms of two bridging azide ligands in a slightly distorted octahedral geometry. The Cd atoms are connected via the 1-oxoisonicotinate and azide ligands into a two-dimensional coordination network. The crystal structure involves O—H⋯N and O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2961384 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613842010-12-30 Poly[diaquabis(μ(2)-azido-κ(2) N (1):N (1))bis(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)] Wang, Zhi-Xiang Li, Xiu-Bing Sun, Bai-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(2)(C(6)H(4)NO(3))(2)(N(3))(2)(H(2)O)(2)](n), one Cd(II) atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octahedral geometry. The other Cd(II) atom, also lying on an inversion center, is coordinated by four O atoms from two bridging 1-oxoisonicotinate ligands and two water molecules and two N atoms of two bridging azide ligands in a slightly distorted octahedral geometry. The Cd atoms are connected via the 1-oxoisonicotinate and azide ligands into a two-dimensional coordination network. The crystal structure involves O—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961384/ /pubmed/21202481 http://dx.doi.org/10.1107/S1600536808013196 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Zhi-Xiang Li, Xiu-Bing Sun, Bai-Wang Poly[diaquabis(μ(2)-azido-κ(2) N (1):N (1))bis(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)] |
title | Poly[diaquabis(μ(2)-azido-κ(2)
N
(1):N
(1))bis(μ(3)-1-oxoisonicotinato-κ(3)
O:O′:O′′)dicadmium(II)] |
title_full | Poly[diaquabis(μ(2)-azido-κ(2)
N
(1):N
(1))bis(μ(3)-1-oxoisonicotinato-κ(3)
O:O′:O′′)dicadmium(II)] |
title_fullStr | Poly[diaquabis(μ(2)-azido-κ(2)
N
(1):N
(1))bis(μ(3)-1-oxoisonicotinato-κ(3)
O:O′:O′′)dicadmium(II)] |
title_full_unstemmed | Poly[diaquabis(μ(2)-azido-κ(2)
N
(1):N
(1))bis(μ(3)-1-oxoisonicotinato-κ(3)
O:O′:O′′)dicadmium(II)] |
title_short | Poly[diaquabis(μ(2)-azido-κ(2)
N
(1):N
(1))bis(μ(3)-1-oxoisonicotinato-κ(3)
O:O′:O′′)dicadmium(II)] |
title_sort | poly[diaquabis(μ(2)-azido-κ(2)
n
(1):n
(1))bis(μ(3)-1-oxoisonicotinato-κ(3)
o:o′:o′′)dicadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961384/ https://www.ncbi.nlm.nih.gov/pubmed/21202481 http://dx.doi.org/10.1107/S1600536808013196 |
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