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Poly[diaqua­bis(μ(2)-azido-κ(2) N (1):N (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)]

In the title compound, [Cd(2)(C(6)H(4)NO(3))(2)(N(3))(2)(H(2)O)(2)](n), one Cd(II) atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octa­hedral geometry. The o...

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Detalles Bibliográficos
Autores principales: Wang, Zhi-Xiang, Li, Xiu-Bing, Sun, Bai-Wang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961384/
https://www.ncbi.nlm.nih.gov/pubmed/21202481
http://dx.doi.org/10.1107/S1600536808013196
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author Wang, Zhi-Xiang
Li, Xiu-Bing
Sun, Bai-Wang
author_facet Wang, Zhi-Xiang
Li, Xiu-Bing
Sun, Bai-Wang
author_sort Wang, Zhi-Xiang
collection PubMed
description In the title compound, [Cd(2)(C(6)H(4)NO(3))(2)(N(3))(2)(H(2)O)(2)](n), one Cd(II) atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octa­hedral geometry. The other Cd(II) atom, also lying on an inversion center, is coordinated by four O atoms from two bridging 1-oxoisonicotinate ligands and two water mol­ecules and two N atoms of two bridging azide ligands in a slightly distorted octa­hedral geometry. The Cd atoms are connected via the 1-oxoisonicotinate and azide ligands into a two-dimensional coordination network. The crystal structure involves O—H⋯N and O—H⋯O hydrogen bonds.
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spelling pubmed-29613842010-12-30 Poly[diaqua­bis(μ(2)-azido-κ(2) N (1):N (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)] Wang, Zhi-Xiang Li, Xiu-Bing Sun, Bai-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(2)(C(6)H(4)NO(3))(2)(N(3))(2)(H(2)O)(2)](n), one Cd(II) atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octa­hedral geometry. The other Cd(II) atom, also lying on an inversion center, is coordinated by four O atoms from two bridging 1-oxoisonicotinate ligands and two water mol­ecules and two N atoms of two bridging azide ligands in a slightly distorted octa­hedral geometry. The Cd atoms are connected via the 1-oxoisonicotinate and azide ligands into a two-dimensional coordination network. The crystal structure involves O—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961384/ /pubmed/21202481 http://dx.doi.org/10.1107/S1600536808013196 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zhi-Xiang
Li, Xiu-Bing
Sun, Bai-Wang
Poly[diaqua­bis(μ(2)-azido-κ(2) N (1):N (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)]
title Poly[diaqua­bis(μ(2)-azido-κ(2) N (1):N (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)]
title_full Poly[diaqua­bis(μ(2)-azido-κ(2) N (1):N (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)]
title_fullStr Poly[diaqua­bis(μ(2)-azido-κ(2) N (1):N (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)]
title_full_unstemmed Poly[diaqua­bis(μ(2)-azido-κ(2) N (1):N (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)]
title_short Poly[diaqua­bis(μ(2)-azido-κ(2) N (1):N (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) O:O′:O′′)dicadmium(II)]
title_sort poly[diaqua­bis(μ(2)-azido-κ(2) n (1):n (1))bis­(μ(3)-1-oxoisonicotinato-κ(3) o:o′:o′′)dicadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961384/
https://www.ncbi.nlm.nih.gov/pubmed/21202481
http://dx.doi.org/10.1107/S1600536808013196
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