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2-(4-Iodophenyl)-5-methyl-3-methylsulfinyl-1-benzofuran
The title compound, C(16)H(13)IO(2)S, was prepared by the oxidation of 2-(4-iodophenyl)-5-methyl-3-methylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The 4-iodophenyl ring makes a dihedral angle of 37.97 (9)° with the plane of the benzofuran fragment, and the O atom and the methyl gr...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961388/ https://www.ncbi.nlm.nih.gov/pubmed/21202580 http://dx.doi.org/10.1107/S1600536808013706 |
Sumario: | The title compound, C(16)H(13)IO(2)S, was prepared by the oxidation of 2-(4-iodophenyl)-5-methyl-3-methylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The 4-iodophenyl ring makes a dihedral angle of 37.97 (9)° with the plane of the benzofuran fragment, and the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of this plane. The molecular packing is stabilized by C—H⋯π interactions between H atoms on the 4-iodophenyl ring and the benzofuran rings, and by an I⋯O halogen bond of 3.252 (2) Å with a nearly linear C—I⋯O angle of 163.06 (8)°. In addition, the stacked molecules exhibit inversion-related S⋯O contacts [3.209 (2) Å] involving the sulfinyl groups. |
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