Bis{2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ(2) N,O}nickel(II) N,N-dimethyl­formamide disolvate

The Ni atom in the title compound, [Ni(C(17)H(15)N(2)O)(2)]·2C(3)H(7)NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolate ligand in a square-planar coordination environment. The mol­ecule is linked to a solvent mol­...

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Autores principales: Ali, Hapipah M., Mohamed Mustafa, Mohamed Ibrahim, Rizal, Mohd. Razali, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961391/
https://www.ncbi.nlm.nih.gov/pubmed/21202476
http://dx.doi.org/10.1107/S1600536808012968
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author Ali, Hapipah M.
Mohamed Mustafa, Mohamed Ibrahim
Rizal, Mohd. Razali
Ng, Seik Weng
author_facet Ali, Hapipah M.
Mohamed Mustafa, Mohamed Ibrahim
Rizal, Mohd. Razali
Ng, Seik Weng
author_sort Ali, Hapipah M.
collection PubMed
description The Ni atom in the title compound, [Ni(C(17)H(15)N(2)O)(2)]·2C(3)H(7)NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolate ligand in a square-planar coordination environment. The mol­ecule is linked to a solvent mol­ecule by an indole–dimethyl­formamide N—H⋯O hydrogen bond.
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spelling pubmed-29613912010-12-30 Bis{2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ(2) N,O}nickel(II) N,N-dimethyl­formamide disolvate Ali, Hapipah M. Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd. Razali Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni atom in the title compound, [Ni(C(17)H(15)N(2)O)(2)]·2C(3)H(7)NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolate ligand in a square-planar coordination environment. The mol­ecule is linked to a solvent mol­ecule by an indole–dimethyl­formamide N—H⋯O hydrogen bond. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961391/ /pubmed/21202476 http://dx.doi.org/10.1107/S1600536808012968 Text en © Ali et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ali, Hapipah M.
Mohamed Mustafa, Mohamed Ibrahim
Rizal, Mohd. Razali
Ng, Seik Weng
Bis{2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ(2) N,O}nickel(II) N,N-dimethyl­formamide disolvate
title Bis{2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ(2) N,O}nickel(II) N,N-dimethyl­formamide disolvate
title_full Bis{2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ(2) N,O}nickel(II) N,N-dimethyl­formamide disolvate
title_fullStr Bis{2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ(2) N,O}nickel(II) N,N-dimethyl­formamide disolvate
title_full_unstemmed Bis{2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ(2) N,O}nickel(II) N,N-dimethyl­formamide disolvate
title_short Bis{2-[2-(1H-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ(2) N,O}nickel(II) N,N-dimethyl­formamide disolvate
title_sort bis{2-[2-(1h-indol-3-yl)ethyl­imino­meth­yl]phenolato-κ(2) n,o}nickel(ii) n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961391/
https://www.ncbi.nlm.nih.gov/pubmed/21202476
http://dx.doi.org/10.1107/S1600536808012968
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AT ngseikweng bis221hindol3ylethyliminomethylphenolatok2nonickeliinndimethylformamidedisolvate

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