μ-Bis(diphenyl­phosphan­yl)borato-κ(2) P:P′-bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II)] tetrachloridoferrate(III) chloro­form solvate

The title compound, [Fe(2)(C(5)H(5))(2)(C(24)H(22)BP(2))(CO)(4)][FeCl(4)]·CHCl(3), is an oxidation product of CpFe(CO)(2)PPh(2)BH(3). One pair of phenyl rings attached to the two different P atoms are almost parallel, as are the other pair [dihedral angles = 8.7 (5) and 8.9 (5)°]. The planes of the...

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Detalles Bibliográficos
Autores principales: Dornhaus, Franz, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961392/
https://www.ncbi.nlm.nih.gov/pubmed/21202516
http://dx.doi.org/10.1107/S1600536808014931
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author Dornhaus, Franz
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Dornhaus, Franz
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Dornhaus, Franz
collection PubMed
description The title compound, [Fe(2)(C(5)H(5))(2)(C(24)H(22)BP(2))(CO)(4)][FeCl(4)]·CHCl(3), is an oxidation product of CpFe(CO)(2)PPh(2)BH(3). One pair of phenyl rings attached to the two different P atoms are almost parallel, as are the other pair [dihedral angles = 8.7 (5) and 8.9 (5)°]. The planes of the two cyclo­penta­dienyl rings are inclined by 26.8 (7)° with respect to each other. The carbonyl groups at each Fe atom are almost perpendicular [C—Fe—C = 92.6 (6) and 94.3 (5)°].
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spelling pubmed-29613922010-12-30 μ-Bis(diphenyl­phosphan­yl)borato-κ(2) P:P′-bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II)] tetrachloridoferrate(III) chloro­form solvate Dornhaus, Franz Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(2)(C(5)H(5))(2)(C(24)H(22)BP(2))(CO)(4)][FeCl(4)]·CHCl(3), is an oxidation product of CpFe(CO)(2)PPh(2)BH(3). One pair of phenyl rings attached to the two different P atoms are almost parallel, as are the other pair [dihedral angles = 8.7 (5) and 8.9 (5)°]. The planes of the two cyclo­penta­dienyl rings are inclined by 26.8 (7)° with respect to each other. The carbonyl groups at each Fe atom are almost perpendicular [C—Fe—C = 92.6 (6) and 94.3 (5)°]. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961392/ /pubmed/21202516 http://dx.doi.org/10.1107/S1600536808014931 Text en © Dornhaus et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dornhaus, Franz
Lerner, Hans-Wolfram
Bolte, Michael
μ-Bis(diphenyl­phosphan­yl)borato-κ(2) P:P′-bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II)] tetrachloridoferrate(III) chloro­form solvate
title μ-Bis(diphenyl­phosphan­yl)borato-κ(2) P:P′-bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II)] tetrachloridoferrate(III) chloro­form solvate
title_full μ-Bis(diphenyl­phosphan­yl)borato-κ(2) P:P′-bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II)] tetrachloridoferrate(III) chloro­form solvate
title_fullStr μ-Bis(diphenyl­phosphan­yl)borato-κ(2) P:P′-bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II)] tetrachloridoferrate(III) chloro­form solvate
title_full_unstemmed μ-Bis(diphenyl­phosphan­yl)borato-κ(2) P:P′-bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II)] tetrachloridoferrate(III) chloro­form solvate
title_short μ-Bis(diphenyl­phosphan­yl)borato-κ(2) P:P′-bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II)] tetrachloridoferrate(III) chloro­form solvate
title_sort μ-bis(diphenyl­phosphan­yl)borato-κ(2) p:p′-bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(ii)] tetrachloridoferrate(iii) chloro­form solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961392/
https://www.ncbi.nlm.nih.gov/pubmed/21202516
http://dx.doi.org/10.1107/S1600536808014931
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AT lernerhanswolfram mbisdiphenylphosphanylboratok2ppbisdicarbonylē5cyclopentadienylironiitetrachloridoferrateiiichloroformsolvate
AT boltemichael mbisdiphenylphosphanylboratok2ppbisdicarbonylē5cyclopentadienylironiitetrachloridoferrateiiichloroformsolvate

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