Chlorido(pyridine-2-carbaldehyde oximato-κ(2) N,N′)(pyridine-2-carbaldehyde oxime-κ(2) N,N′)copper(II)

In the title compound, [Cu(C(6)H(5)N(2)O)Cl(C(6)H(6)N(2)O)], the Cu atom is coordinated by one neutral and one deprotonated pyridine-2-carboxaldehyde oxime (pco) ligand, resulting in the formation of two five-membered CuN(2)C(2) rings. Together with the additional coordinating chloride anion, the co...

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Detalles Bibliográficos
Autores principales: Wu, Genhua, Wu, Dayu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961395/
https://www.ncbi.nlm.nih.gov/pubmed/21202510
http://dx.doi.org/10.1107/S1600536808014748
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author Wu, Genhua
Wu, Dayu
author_facet Wu, Genhua
Wu, Dayu
author_sort Wu, Genhua
collection PubMed
description In the title compound, [Cu(C(6)H(5)N(2)O)Cl(C(6)H(6)N(2)O)], the Cu atom is coordinated by one neutral and one deprotonated pyridine-2-carboxaldehyde oxime (pco) ligand, resulting in the formation of two five-membered CuN(2)C(2) rings. Together with the additional coordinating chloride anion, the coordination polyhedron of copper is best described as a distorted square-pyramid, the distortion parameter being 0.288. The two organic ligands are linked by an intramolecular O—H⋯O hydrogen bond.
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spelling pubmed-29613952010-12-30 Chlorido(pyridine-2-carbaldehyde oximato-κ(2) N,N′)(pyridine-2-carbaldehyde oxime-κ(2) N,N′)copper(II) Wu, Genhua Wu, Dayu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(5)N(2)O)Cl(C(6)H(6)N(2)O)], the Cu atom is coordinated by one neutral and one deprotonated pyridine-2-carboxaldehyde oxime (pco) ligand, resulting in the formation of two five-membered CuN(2)C(2) rings. Together with the additional coordinating chloride anion, the coordination polyhedron of copper is best described as a distorted square-pyramid, the distortion parameter being 0.288. The two organic ligands are linked by an intramolecular O—H⋯O hydrogen bond. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961395/ /pubmed/21202510 http://dx.doi.org/10.1107/S1600536808014748 Text en © Wu and Wu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Genhua
Wu, Dayu
Chlorido(pyridine-2-carbaldehyde oximato-κ(2) N,N′)(pyridine-2-carbaldehyde oxime-κ(2) N,N′)copper(II)
title Chlorido(pyridine-2-carbaldehyde oximato-κ(2) N,N′)(pyridine-2-carbaldehyde oxime-κ(2) N,N′)copper(II)
title_full Chlorido(pyridine-2-carbaldehyde oximato-κ(2) N,N′)(pyridine-2-carbaldehyde oxime-κ(2) N,N′)copper(II)
title_fullStr Chlorido(pyridine-2-carbaldehyde oximato-κ(2) N,N′)(pyridine-2-carbaldehyde oxime-κ(2) N,N′)copper(II)
title_full_unstemmed Chlorido(pyridine-2-carbaldehyde oximato-κ(2) N,N′)(pyridine-2-carbaldehyde oxime-κ(2) N,N′)copper(II)
title_short Chlorido(pyridine-2-carbaldehyde oximato-κ(2) N,N′)(pyridine-2-carbaldehyde oxime-κ(2) N,N′)copper(II)
title_sort chlorido(pyridine-2-carbaldehyde oximato-κ(2) n,n′)(pyridine-2-carbaldehyde oxime-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961395/
https://www.ncbi.nlm.nih.gov/pubmed/21202510
http://dx.doi.org/10.1107/S1600536808014748
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AT wudayu chloridopyridine2carbaldehydeoximatok2nnpyridine2carbaldehydeoximek2nncopperii

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