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μ-Aqua-bis­(μ-4-methyl­benzoato-κ(2) O:O′)bis­[(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)]

In the title binuclear complex, [Fe(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], the Fe(II) ion is six-coordinated by three carboxylate O atoms from three 4-methyl­benzoate ligands, two N atoms from two 1,10-phenanthroline ligands and one bridging aqua ligand in a distorted octa­hedral geometry. T...

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Detalles Bibliográficos
Autor principal: Feng, Sun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961397/
https://www.ncbi.nlm.nih.gov/pubmed/21202501
http://dx.doi.org/10.1107/S1600536808014207
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author Feng, Sun
author_facet Feng, Sun
author_sort Feng, Sun
collection PubMed
description In the title binuclear complex, [Fe(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], the Fe(II) ion is six-coordinated by three carboxylate O atoms from three 4-methyl­benzoate ligands, two N atoms from two 1,10-phenanthroline ligands and one bridging aqua ligand in a distorted octa­hedral geometry. The coordinated water mol­ecule acting as the bridging ligand is located on a twofold axes and the complex mol­ecule displays C (2) mol­ecular symmetry. The Fe⋯Fe separation in the binuclear complex is 3.490 (3) Å. The crystal structure is stabilized by hydrogen bonding and π–π stacking inter­actions [the centroid–centroid distance between adjacent 1,10-phenanthroline ring systems is 3.653 (2) Å, and that between the 1,10-phenanthroline ring system and the phenyl ring of the 4-methyl­benzoate unit of a neighbouring complex is 3.622 (3) Å].
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spelling pubmed-29613972010-12-30 μ-Aqua-bis­(μ-4-methyl­benzoato-κ(2) O:O′)bis­[(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)] Feng, Sun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear complex, [Fe(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], the Fe(II) ion is six-coordinated by three carboxylate O atoms from three 4-methyl­benzoate ligands, two N atoms from two 1,10-phenanthroline ligands and one bridging aqua ligand in a distorted octa­hedral geometry. The coordinated water mol­ecule acting as the bridging ligand is located on a twofold axes and the complex mol­ecule displays C (2) mol­ecular symmetry. The Fe⋯Fe separation in the binuclear complex is 3.490 (3) Å. The crystal structure is stabilized by hydrogen bonding and π–π stacking inter­actions [the centroid–centroid distance between adjacent 1,10-phenanthroline ring systems is 3.653 (2) Å, and that between the 1,10-phenanthroline ring system and the phenyl ring of the 4-methyl­benzoate unit of a neighbouring complex is 3.622 (3) Å]. International Union of Crystallography 2008-05-17 /pmc/articles/PMC2961397/ /pubmed/21202501 http://dx.doi.org/10.1107/S1600536808014207 Text en © Sun Feng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Feng, Sun
μ-Aqua-bis­(μ-4-methyl­benzoato-κ(2) O:O′)bis­[(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)]
title μ-Aqua-bis­(μ-4-methyl­benzoato-κ(2) O:O′)bis­[(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)]
title_full μ-Aqua-bis­(μ-4-methyl­benzoato-κ(2) O:O′)bis­[(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)]
title_fullStr μ-Aqua-bis­(μ-4-methyl­benzoato-κ(2) O:O′)bis­[(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)]
title_full_unstemmed μ-Aqua-bis­(μ-4-methyl­benzoato-κ(2) O:O′)bis­[(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)]
title_short μ-Aqua-bis­(μ-4-methyl­benzoato-κ(2) O:O′)bis­[(4-methyl­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)]
title_sort μ-aqua-bis­(μ-4-methyl­benzoato-κ(2) o:o′)bis­[(4-methyl­benzoato-κo)(1,10-phenanthroline-κ(2) n,n′)iron(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961397/
https://www.ncbi.nlm.nih.gov/pubmed/21202501
http://dx.doi.org/10.1107/S1600536808014207
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