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μ-Aqua-bis(μ-4-methylbenzoato-κ(2) O:O′)bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)]
In the title binuclear complex, [Fe(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], the Fe(II) ion is six-coordinated by three carboxylate O atoms from three 4-methylbenzoate ligands, two N atoms from two 1,10-phenanthroline ligands and one bridging aqua ligand in a distorted octahedral geometry. T...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961397/ https://www.ncbi.nlm.nih.gov/pubmed/21202501 http://dx.doi.org/10.1107/S1600536808014207 |
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author | Feng, Sun |
author_facet | Feng, Sun |
author_sort | Feng, Sun |
collection | PubMed |
description | In the title binuclear complex, [Fe(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], the Fe(II) ion is six-coordinated by three carboxylate O atoms from three 4-methylbenzoate ligands, two N atoms from two 1,10-phenanthroline ligands and one bridging aqua ligand in a distorted octahedral geometry. The coordinated water molecule acting as the bridging ligand is located on a twofold axes and the complex molecule displays C (2) molecular symmetry. The Fe⋯Fe separation in the binuclear complex is 3.490 (3) Å. The crystal structure is stabilized by hydrogen bonding and π–π stacking interactions [the centroid–centroid distance between adjacent 1,10-phenanthroline ring systems is 3.653 (2) Å, and that between the 1,10-phenanthroline ring system and the phenyl ring of the 4-methylbenzoate unit of a neighbouring complex is 3.622 (3) Å]. |
format | Text |
id | pubmed-2961397 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613972010-12-30 μ-Aqua-bis(μ-4-methylbenzoato-κ(2) O:O′)bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)] Feng, Sun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear complex, [Fe(2)(C(8)H(7)O(2))(4)(C(12)H(8)N(2))(2)(H(2)O)], the Fe(II) ion is six-coordinated by three carboxylate O atoms from three 4-methylbenzoate ligands, two N atoms from two 1,10-phenanthroline ligands and one bridging aqua ligand in a distorted octahedral geometry. The coordinated water molecule acting as the bridging ligand is located on a twofold axes and the complex molecule displays C (2) molecular symmetry. The Fe⋯Fe separation in the binuclear complex is 3.490 (3) Å. The crystal structure is stabilized by hydrogen bonding and π–π stacking interactions [the centroid–centroid distance between adjacent 1,10-phenanthroline ring systems is 3.653 (2) Å, and that between the 1,10-phenanthroline ring system and the phenyl ring of the 4-methylbenzoate unit of a neighbouring complex is 3.622 (3) Å]. International Union of Crystallography 2008-05-17 /pmc/articles/PMC2961397/ /pubmed/21202501 http://dx.doi.org/10.1107/S1600536808014207 Text en © Sun Feng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Feng, Sun μ-Aqua-bis(μ-4-methylbenzoato-κ(2) O:O′)bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)iron(II)] |
title | μ-Aqua-bis(μ-4-methylbenzoato-κ(2)
O:O′)bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)iron(II)] |
title_full | μ-Aqua-bis(μ-4-methylbenzoato-κ(2)
O:O′)bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)iron(II)] |
title_fullStr | μ-Aqua-bis(μ-4-methylbenzoato-κ(2)
O:O′)bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)iron(II)] |
title_full_unstemmed | μ-Aqua-bis(μ-4-methylbenzoato-κ(2)
O:O′)bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)iron(II)] |
title_short | μ-Aqua-bis(μ-4-methylbenzoato-κ(2)
O:O′)bis[(4-methylbenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)iron(II)] |
title_sort | μ-aqua-bis(μ-4-methylbenzoato-κ(2)
o:o′)bis[(4-methylbenzoato-κo)(1,10-phenanthroline-κ(2)
n,n′)iron(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961397/ https://www.ncbi.nlm.nih.gov/pubmed/21202501 http://dx.doi.org/10.1107/S1600536808014207 |
work_keys_str_mv | AT fengsun maquabism4methylbenzoatok2oobis4methylbenzoatoko110phenanthrolinek2nnironii |