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Hexaaquahexakis(μ(2)-3,5-diamino-4H-1,2,4-triazole)trinickel(II) tris(hexafluoridosilicate) icosahydrate
The trinuclear cation of the title compound, [Ni(3)(C(2)H(5)N(5))(6)(H(2)O)(6)][SiF(6)](3)·20H(2)O, has the six 3,5-diamino-1,2,4-triazole ligands each bridging two metal atoms; the metal atom in the middle, which lies on a special position (of 32 site symmetry), is connected to six N atoms in an oc...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961398/ https://www.ncbi.nlm.nih.gov/pubmed/21202489 http://dx.doi.org/10.1107/S1600536808013329 |
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author | Wu, Li-Ping Zhao, Shu-Ming Zhang, Guo-Fang Ng, Seik Weng |
author_facet | Wu, Li-Ping Zhao, Shu-Ming Zhang, Guo-Fang Ng, Seik Weng |
author_sort | Wu, Li-Ping |
collection | PubMed |
description | The trinuclear cation of the title compound, [Ni(3)(C(2)H(5)N(5))(6)(H(2)O)(6)][SiF(6)](3)·20H(2)O, has the six 3,5-diamino-1,2,4-triazole ligands each bridging two metal atoms; the metal atom in the middle, which lies on a special position (of 32 site symmetry), is connected to six N atoms in an octahedral geometry. The other metal atom, which lies on a special position (of 3 site symmetry), is connected to three N atoms and three O atoms. One hexafluroridosilicate anion lies on a site of 3 symmetry and the other lies on a site of [Image: see text] symmetry. The hexacation, dianions and uncoordinated water molecules interact through hydrogen bonds to form a three-dimensional network. One uncoordinated water molecule is disordered, with site occupancy 0.3. |
format | Text |
id | pubmed-2961398 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29613982010-12-30 Hexaaquahexakis(μ(2)-3,5-diamino-4H-1,2,4-triazole)trinickel(II) tris(hexafluoridosilicate) icosahydrate Wu, Li-Ping Zhao, Shu-Ming Zhang, Guo-Fang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The trinuclear cation of the title compound, [Ni(3)(C(2)H(5)N(5))(6)(H(2)O)(6)][SiF(6)](3)·20H(2)O, has the six 3,5-diamino-1,2,4-triazole ligands each bridging two metal atoms; the metal atom in the middle, which lies on a special position (of 32 site symmetry), is connected to six N atoms in an octahedral geometry. The other metal atom, which lies on a special position (of 3 site symmetry), is connected to three N atoms and three O atoms. One hexafluroridosilicate anion lies on a site of 3 symmetry and the other lies on a site of [Image: see text] symmetry. The hexacation, dianions and uncoordinated water molecules interact through hydrogen bonds to form a three-dimensional network. One uncoordinated water molecule is disordered, with site occupancy 0.3. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961398/ /pubmed/21202489 http://dx.doi.org/10.1107/S1600536808013329 Text en © Wu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Li-Ping Zhao, Shu-Ming Zhang, Guo-Fang Ng, Seik Weng Hexaaquahexakis(μ(2)-3,5-diamino-4H-1,2,4-triazole)trinickel(II) tris(hexafluoridosilicate) icosahydrate |
title | Hexaaquahexakis(μ(2)-3,5-diamino-4H-1,2,4-triazole)trinickel(II) tris(hexafluoridosilicate) icosahydrate |
title_full | Hexaaquahexakis(μ(2)-3,5-diamino-4H-1,2,4-triazole)trinickel(II) tris(hexafluoridosilicate) icosahydrate |
title_fullStr | Hexaaquahexakis(μ(2)-3,5-diamino-4H-1,2,4-triazole)trinickel(II) tris(hexafluoridosilicate) icosahydrate |
title_full_unstemmed | Hexaaquahexakis(μ(2)-3,5-diamino-4H-1,2,4-triazole)trinickel(II) tris(hexafluoridosilicate) icosahydrate |
title_short | Hexaaquahexakis(μ(2)-3,5-diamino-4H-1,2,4-triazole)trinickel(II) tris(hexafluoridosilicate) icosahydrate |
title_sort | hexaaquahexakis(μ(2)-3,5-diamino-4h-1,2,4-triazole)trinickel(ii) tris(hexafluoridosilicate) icosahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961398/ https://www.ncbi.nlm.nih.gov/pubmed/21202489 http://dx.doi.org/10.1107/S1600536808013329 |
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