Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN (2)}manganese(II) dihydrate

The title compound, [Mn(C(4)H(3)N(8))(2)(H(2)O)(4)]·2H(2)O, represents the first structurally characterized transition metal complex of the 1,2-bis­(tetra­zol-5-yl)ethene ligand. The complex mol­ecule occupies a special position on an inversion centre and the Mn atom has a tetra­gonally distorted oc...

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Detalles Bibliográficos
Autor principal: Hu, Tuoping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961402/
https://www.ncbi.nlm.nih.gov/pubmed/21202464
http://dx.doi.org/10.1107/S1600536808012464
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author Hu, Tuoping
author_facet Hu, Tuoping
author_sort Hu, Tuoping
collection PubMed
description The title compound, [Mn(C(4)H(3)N(8))(2)(H(2)O)(4)]·2H(2)O, represents the first structurally characterized transition metal complex of the 1,2-bis­(tetra­zol-5-yl)ethene ligand. The complex mol­ecule occupies a special position on an inversion centre and the Mn atom has a tetra­gonally distorted octa­hedral coordination. The bis­(tetra­zolyl)ethene ligand is planar within 0.0366 (7) Å. All ‘active’ H atoms participate in hydrogen bonds, which link mol­ecules of the complex and the uncoordinated water mol­ecules into an infinite three-dimensional framework.
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spelling pubmed-29614022010-12-30 Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN (2)}manganese(II) dihydrate Hu, Tuoping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(4)H(3)N(8))(2)(H(2)O)(4)]·2H(2)O, represents the first structurally characterized transition metal complex of the 1,2-bis­(tetra­zol-5-yl)ethene ligand. The complex mol­ecule occupies a special position on an inversion centre and the Mn atom has a tetra­gonally distorted octa­hedral coordination. The bis­(tetra­zolyl)ethene ligand is planar within 0.0366 (7) Å. All ‘active’ H atoms participate in hydrogen bonds, which link mol­ecules of the complex and the uncoordinated water mol­ecules into an infinite three-dimensional framework. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961402/ /pubmed/21202464 http://dx.doi.org/10.1107/S1600536808012464 Text en © Tuoping Hu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Tuoping
Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN (2)}manganese(II) dihydrate
title Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN (2)}manganese(II) dihydrate
title_full Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN (2)}manganese(II) dihydrate
title_fullStr Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN (2)}manganese(II) dihydrate
title_full_unstemmed Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN (2)}manganese(II) dihydrate
title_short Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN (2)}manganese(II) dihydrate
title_sort tetra­aqua­bis{5-[2-(1h-tetrazol-5-yl)ethenyl]pyrazolato-κn (2)}manganese(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961402/
https://www.ncbi.nlm.nih.gov/pubmed/21202464
http://dx.doi.org/10.1107/S1600536808012464
work_keys_str_mv AT hutuoping tetraaquabis521htetrazol5ylethenylpyrazolatokn2manganeseiidihydrate

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