Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV) toluene disolvate

In the title compound, [Hf(C(5)H(4)F(3)O(2))(4)]·2C(7)H(8), the Hf(IV) atom, lying on a twofold rotation axis, is coordinated by eight O atoms from four 1,1,1-trifluoro­acetyl­acetonate ligands with an average Hf—O distance of 2.173 (1) Å and O—Hf—O bite angles of 75.69 (5) and 75.54 (5)°. The coord...

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Detalles Bibliográficos
Autores principales: Viljoen, J. Augustinus, Muller, Alfred, Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961404/
https://www.ncbi.nlm.nih.gov/pubmed/21202519
http://dx.doi.org/10.1107/S1600536808015237
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author Viljoen, J. Augustinus
Muller, Alfred
Roodt, Andreas
author_facet Viljoen, J. Augustinus
Muller, Alfred
Roodt, Andreas
author_sort Viljoen, J. Augustinus
collection PubMed
description In the title compound, [Hf(C(5)H(4)F(3)O(2))(4)]·2C(7)H(8), the Hf(IV) atom, lying on a twofold rotation axis, is coordinated by eight O atoms from four 1,1,1-trifluoro­acetyl­acetonate ligands with an average Hf—O distance of 2.173 (1) Å and O—Hf—O bite angles of 75.69 (5) and 75.54 (5)°. The coordination polyhedron shows a slightly distorted Archimedean square antiprismatic geometry. The asymmetric unit contains a toluene solvent mol­ecule. The crystal structure involves C—H⋯.F hydrogen bonds.
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spelling pubmed-29614042010-12-30 Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV) toluene disolvate Viljoen, J. Augustinus Muller, Alfred Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hf(C(5)H(4)F(3)O(2))(4)]·2C(7)H(8), the Hf(IV) atom, lying on a twofold rotation axis, is coordinated by eight O atoms from four 1,1,1-trifluoro­acetyl­acetonate ligands with an average Hf—O distance of 2.173 (1) Å and O—Hf—O bite angles of 75.69 (5) and 75.54 (5)°. The coordination polyhedron shows a slightly distorted Archimedean square antiprismatic geometry. The asymmetric unit contains a toluene solvent mol­ecule. The crystal structure involves C—H⋯.F hydrogen bonds. International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961404/ /pubmed/21202519 http://dx.doi.org/10.1107/S1600536808015237 Text en © Viljoen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Viljoen, J. Augustinus
Muller, Alfred
Roodt, Andreas
Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV) toluene disolvate
title Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV) toluene disolvate
title_full Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV) toluene disolvate
title_fullStr Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV) toluene disolvate
title_full_unstemmed Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV) toluene disolvate
title_short Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV) toluene disolvate
title_sort tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) o,o′)hafnium(iv) toluene disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961404/
https://www.ncbi.nlm.nih.gov/pubmed/21202519
http://dx.doi.org/10.1107/S1600536808015237
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AT mulleralfred tetrakis111trifluoroacetylacetonatok2oohafniumivtoluenedisolvate
AT roodtandreas tetrakis111trifluoroacetylacetonatok2oohafniumivtoluenedisolvate

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