trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ(2) N (1),S)nickel(II)

The Ni atom in the centrosymmetric title compound, [Ni(C(10)H(9)N(4)S)(2)], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH(2) frament is planar. Adjacent mol­ecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bon...

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Detalles Bibliográficos
Autores principales: Rizal, Mohd. Razali, Ali, Hapipah M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961409/
https://www.ncbi.nlm.nih.gov/pubmed/21202507
http://dx.doi.org/10.1107/S1600536808014293
Descripción
Sumario:The Ni atom in the centrosymmetric title compound, [Ni(C(10)H(9)N(4)S)(2)], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH(2) frament is planar. Adjacent mol­ecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acceptor) site of an adjacent mol­ecule, forming a layer motif.

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