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trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ(2) N (1),S)nickel(II)
The Ni atom in the centrosymmetric title compound, [Ni(C(10)H(9)N(4)S)(2)], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH(2) frament is planar. Adjacent molecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bon...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961409/ https://www.ncbi.nlm.nih.gov/pubmed/21202507 http://dx.doi.org/10.1107/S1600536808014293 |
| _version_ | 1782188975837937664 |
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| author | Rizal, Mohd. Razali Ali, Hapipah M. Ng, Seik Weng |
| author_facet | Rizal, Mohd. Razali Ali, Hapipah M. Ng, Seik Weng |
| author_sort | Rizal, Mohd. Razali |
| collection | PubMed |
| description | The Ni atom in the centrosymmetric title compound, [Ni(C(10)H(9)N(4)S)(2)], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH(2) frament is planar. Adjacent molecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acceptor) site of an adjacent molecule, forming a layer motif. |
| format | Text |
| id | pubmed-2961409 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29614092010-12-30 trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ(2) N (1),S)nickel(II) Rizal, Mohd. Razali Ali, Hapipah M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni atom in the centrosymmetric title compound, [Ni(C(10)H(9)N(4)S)(2)], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH(2) frament is planar. Adjacent molecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acceptor) site of an adjacent molecule, forming a layer motif. International Union of Crystallography 2008-05-17 /pmc/articles/PMC2961409/ /pubmed/21202507 http://dx.doi.org/10.1107/S1600536808014293 Text en © Rizal et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Rizal, Mohd. Razali Ali, Hapipah M. Ng, Seik Weng trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ(2) N (1),S)nickel(II) |
| title |
trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ(2)
N
(1),S)nickel(II) |
| title_full |
trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ(2)
N
(1),S)nickel(II) |
| title_fullStr |
trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ(2)
N
(1),S)nickel(II) |
| title_full_unstemmed |
trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ(2)
N
(1),S)nickel(II) |
| title_short |
trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ(2)
N
(1),S)nickel(II) |
| title_sort | trans-bis(1h-indole-3-carbaldehyde thiosemicarbazonato-κ(2)
n
(1),s)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961409/ https://www.ncbi.nlm.nih.gov/pubmed/21202507 http://dx.doi.org/10.1107/S1600536808014293 |
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