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1-(2-Furoyl)-3-(1-naphthyl)thiourea
In the title compound, C(16)H(12)N(2)O(2)S, the carbonylthiourea group forms dihedral angles of 75.4 (1) and 13.1 (2)°, respectively, with the naphthalene ring system and furan ring. The molecule adopts a trans–cis configuration with respect to the positions of the furoyl and naphthyl groups rela...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961410/ https://www.ncbi.nlm.nih.gov/pubmed/21202587 http://dx.doi.org/10.1107/S1600536808012208 |
Sumario: | In the title compound, C(16)H(12)N(2)O(2)S, the carbonylthiourea group forms dihedral angles of 75.4 (1) and 13.1 (2)°, respectively, with the naphthalene ring system and furan ring. The molecule adopts a trans–cis configuration with respect to the positions of the furoyl and naphthyl groups relative to the S atom across the thiourea C—N bonds. This geometry is stabilized by an N—H⋯·O intramolecular hydrogen bond. In the crystal structure, molecules are linked by N—H⋯S hydrogen bonds, forming centrosymmetric dimers which are interlinked through C—H⋯π interactions. |
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