1-(2-Furo­yl)-3-(1-naphth­yl)thio­urea

In the title compound, C(16)H(12)N(2)O(2)S, the carbonyl­thio­urea group forms dihedral angles of 75.4 (1) and 13.1 (2)°, respectively, with the naphthalene ring system and furan ring. The mol­ecule adopts a trans–cis configuration with respect to the positions of the furoyl and naphthyl groups rela...

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Detalles Bibliográficos
Autores principales: Duque, J., Estevez-Hernandez, Osvaldo, Reguera, Edilso, Corrêa, Rodrigo S., Gutierrez Maria, P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961410/
https://www.ncbi.nlm.nih.gov/pubmed/21202587
http://dx.doi.org/10.1107/S1600536808012208
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author Duque, J.
Estevez-Hernandez, Osvaldo
Reguera, Edilso
Corrêa, Rodrigo S.
Gutierrez Maria, P.
author_facet Duque, J.
Estevez-Hernandez, Osvaldo
Reguera, Edilso
Corrêa, Rodrigo S.
Gutierrez Maria, P.
author_sort Duque, J.
collection PubMed
description In the title compound, C(16)H(12)N(2)O(2)S, the carbonyl­thio­urea group forms dihedral angles of 75.4 (1) and 13.1 (2)°, respectively, with the naphthalene ring system and furan ring. The mol­ecule adopts a trans–cis configuration with respect to the positions of the furoyl and naphthyl groups relative to the S atom across the thio­urea C—N bonds. This geometry is stabilized by an N—H⋯·O intra­molecular hydrogen bond. In the crystal structure, mol­ecules are linked by N—H⋯S hydrogen bonds, forming centrosymmetric dimers which are inter­linked through C—H⋯π inter­actions.
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spelling pubmed-29614102010-12-30 1-(2-Furo­yl)-3-(1-naphth­yl)thio­urea Duque, J. Estevez-Hernandez, Osvaldo Reguera, Edilso Corrêa, Rodrigo S. Gutierrez Maria, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(12)N(2)O(2)S, the carbonyl­thio­urea group forms dihedral angles of 75.4 (1) and 13.1 (2)°, respectively, with the naphthalene ring system and furan ring. The mol­ecule adopts a trans–cis configuration with respect to the positions of the furoyl and naphthyl groups relative to the S atom across the thio­urea C—N bonds. This geometry is stabilized by an N—H⋯·O intra­molecular hydrogen bond. In the crystal structure, mol­ecules are linked by N—H⋯S hydrogen bonds, forming centrosymmetric dimers which are inter­linked through C—H⋯π inter­actions. International Union of Crystallography 2008-05-14 /pmc/articles/PMC2961410/ /pubmed/21202587 http://dx.doi.org/10.1107/S1600536808012208 Text en © Duque et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Duque, J.
Estevez-Hernandez, Osvaldo
Reguera, Edilso
Corrêa, Rodrigo S.
Gutierrez Maria, P.
1-(2-Furo­yl)-3-(1-naphth­yl)thio­urea
title 1-(2-Furo­yl)-3-(1-naphth­yl)thio­urea
title_full 1-(2-Furo­yl)-3-(1-naphth­yl)thio­urea
title_fullStr 1-(2-Furo­yl)-3-(1-naphth­yl)thio­urea
title_full_unstemmed 1-(2-Furo­yl)-3-(1-naphth­yl)thio­urea
title_short 1-(2-Furo­yl)-3-(1-naphth­yl)thio­urea
title_sort 1-(2-furo­yl)-3-(1-naphth­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961410/
https://www.ncbi.nlm.nih.gov/pubmed/21202587
http://dx.doi.org/10.1107/S1600536808012208
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AT regueraedilso 12furoyl31naphthylthiourea
AT correarodrigos 12furoyl31naphthylthiourea
AT gutierrezmariap 12furoyl31naphthylthiourea

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