2-(Mesitylmethyl­sulfan­yl)pyridine N-oxide–18-crown-6 (2/1)

In the title compound, 2C(15)H(17)NOS·C(12)H(24)O(6), the asymmetric unit consists of one N-oxide derivative and one-half of the 18-crown-6 ether, which lies on an inversion centre. In the crown ether, the O—C—C—O torsion angles indicate a gauche conformation of the ethyl­eneoxy units, while the C—O...

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Autores principales: Ravindran Durai Nayagam, B., Jebas, Samuel Robinson, Jebaraj Devadasan, J., Schollmeyer, Dieter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961412/
https://www.ncbi.nlm.nih.gov/pubmed/21202705
http://dx.doi.org/10.1107/S1600536808012403
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author Ravindran Durai Nayagam, B.
Jebas, Samuel Robinson
Jebaraj Devadasan, J.
Schollmeyer, Dieter
author_facet Ravindran Durai Nayagam, B.
Jebas, Samuel Robinson
Jebaraj Devadasan, J.
Schollmeyer, Dieter
author_sort Ravindran Durai Nayagam, B.
collection PubMed
description In the title compound, 2C(15)H(17)NOS·C(12)H(24)O(6), the asymmetric unit consists of one N-oxide derivative and one-half of the 18-crown-6 ether, which lies on an inversion centre. In the crown ether, the O—C—C—O torsion angles indicate a gauche conformation of the ethyl­eneoxy units, while the C—O—C—C torsion angles indicate planarity of these segments. In the N-oxide unit, the dihedral angle between the pyridine and benzene rings is 85.88 (12)°. The crystal packing is stabilized by weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions.
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spelling pubmed-29614122010-12-30 2-(Mesitylmethyl­sulfan­yl)pyridine N-oxide–18-crown-6 (2/1) Ravindran Durai Nayagam, B. Jebas, Samuel Robinson Jebaraj Devadasan, J. Schollmeyer, Dieter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, 2C(15)H(17)NOS·C(12)H(24)O(6), the asymmetric unit consists of one N-oxide derivative and one-half of the 18-crown-6 ether, which lies on an inversion centre. In the crown ether, the O—C—C—O torsion angles indicate a gauche conformation of the ethyl­eneoxy units, while the C—O—C—C torsion angles indicate planarity of these segments. In the N-oxide unit, the dihedral angle between the pyridine and benzene rings is 85.88 (12)°. The crystal packing is stabilized by weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961412/ /pubmed/21202705 http://dx.doi.org/10.1107/S1600536808012403 Text en © Ravindran Durai Nayagam et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ravindran Durai Nayagam, B.
Jebas, Samuel Robinson
Jebaraj Devadasan, J.
Schollmeyer, Dieter
2-(Mesitylmethyl­sulfan­yl)pyridine N-oxide–18-crown-6 (2/1)
title 2-(Mesitylmethyl­sulfan­yl)pyridine N-oxide–18-crown-6 (2/1)
title_full 2-(Mesitylmethyl­sulfan­yl)pyridine N-oxide–18-crown-6 (2/1)
title_fullStr 2-(Mesitylmethyl­sulfan­yl)pyridine N-oxide–18-crown-6 (2/1)
title_full_unstemmed 2-(Mesitylmethyl­sulfan­yl)pyridine N-oxide–18-crown-6 (2/1)
title_short 2-(Mesitylmethyl­sulfan­yl)pyridine N-oxide–18-crown-6 (2/1)
title_sort 2-(mesitylmethyl­sulfan­yl)pyridine n-oxide–18-crown-6 (2/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961412/
https://www.ncbi.nlm.nih.gov/pubmed/21202705
http://dx.doi.org/10.1107/S1600536808012403
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