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Aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate

In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking inter­action between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance...

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Detalles Bibliográficos
Autores principales: Li, Hong Liang, Liu, Qi Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961415/
https://www.ncbi.nlm.nih.gov/pubmed/21202525
http://dx.doi.org/10.1107/S1600536808015523
Descripción
Sumario:In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking inter­action between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance = 3.567 (2) Å and a perpendicular distance of 3.394 Å]. The crystal structure also contains inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, linking cations and anions. In addition, there is a short inter­molecular contact [2.784 (6) Å] between an O atom of the coordinated nitrate group and its symmetry-related atom.