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Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate
In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking interaction between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961415/ https://www.ncbi.nlm.nih.gov/pubmed/21202525 http://dx.doi.org/10.1107/S1600536808015523 |
Sumario: | In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking interaction between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance = 3.567 (2) Å and a perpendicular distance of 3.394 Å]. The crystal structure also contains intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, linking cations and anions. In addition, there is a short intermolecular contact [2.784 (6) Å] between an O atom of the coordinated nitrate group and its symmetry-related atom. |
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