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Aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate

In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking inter­action between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance...

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Detalles Bibliográficos
Autores principales: Li, Hong Liang, Liu, Qi Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961415/
https://www.ncbi.nlm.nih.gov/pubmed/21202525
http://dx.doi.org/10.1107/S1600536808015523
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author Li, Hong Liang
Liu, Qi Sheng
author_facet Li, Hong Liang
Liu, Qi Sheng
author_sort Li, Hong Liang
collection PubMed
description In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking inter­action between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance = 3.567 (2) Å and a perpendicular distance of 3.394 Å]. The crystal structure also contains inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, linking cations and anions. In addition, there is a short inter­molecular contact [2.784 (6) Å] between an O atom of the coordinated nitrate group and its symmetry-related atom.
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spelling pubmed-29614152010-12-30 Aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate Li, Hong Liang Liu, Qi Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking inter­action between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance = 3.567 (2) Å and a perpendicular distance of 3.394 Å]. The crystal structure also contains inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, linking cations and anions. In addition, there is a short inter­molecular contact [2.784 (6) Å] between an O atom of the coordinated nitrate group and its symmetry-related atom. International Union of Crystallography 2008-05-30 /pmc/articles/PMC2961415/ /pubmed/21202525 http://dx.doi.org/10.1107/S1600536808015523 Text en © Li and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hong Liang
Liu, Qi Sheng
Aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate
title Aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate
title_full Aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate
title_fullStr Aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate
title_full_unstemmed Aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate
title_short Aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate
title_sort aqua­(2-hydrazino-1,10-phenanthroline)nitratocopper(ii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961415/
https://www.ncbi.nlm.nih.gov/pubmed/21202525
http://dx.doi.org/10.1107/S1600536808015523
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