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Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate
In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking interaction between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961415/ https://www.ncbi.nlm.nih.gov/pubmed/21202525 http://dx.doi.org/10.1107/S1600536808015523 |
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author | Li, Hong Liang Liu, Qi Sheng |
author_facet | Li, Hong Liang Liu, Qi Sheng |
author_sort | Li, Hong Liang |
collection | PubMed |
description | In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking interaction between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance = 3.567 (2) Å and a perpendicular distance of 3.394 Å]. The crystal structure also contains intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, linking cations and anions. In addition, there is a short intermolecular contact [2.784 (6) Å] between an O atom of the coordinated nitrate group and its symmetry-related atom. |
format | Text |
id | pubmed-2961415 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29614152010-12-30 Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate Li, Hong Liang Liu, Qi Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π–π stacking interaction between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid–centroid distance = 3.567 (2) Å and a perpendicular distance of 3.394 Å]. The crystal structure also contains intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, linking cations and anions. In addition, there is a short intermolecular contact [2.784 (6) Å] between an O atom of the coordinated nitrate group and its symmetry-related atom. International Union of Crystallography 2008-05-30 /pmc/articles/PMC2961415/ /pubmed/21202525 http://dx.doi.org/10.1107/S1600536808015523 Text en © Li and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Hong Liang Liu, Qi Sheng Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate |
title | Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate |
title_full | Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate |
title_fullStr | Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate |
title_full_unstemmed | Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate |
title_short | Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate |
title_sort | aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(ii) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961415/ https://www.ncbi.nlm.nih.gov/pubmed/21202525 http://dx.doi.org/10.1107/S1600536808015523 |
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