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Poly[aqua[μ(3)-5-(2-carboxylatophenyl)-1H-tetrazolato]zinc(II)]
The title coordination polymer, [Zn(C(8)H(4)N(4)O(2))(H(2)O)](n), was prepared by the hydrothermal reaction of zinc nitrate and 2-(1H-tetrazol-5-yl)benzoic acid. Two types of coordinated zinc cations exist in the structure. One is tetrahedrally coordinated by two O and two N from two ligands, the...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961416/ https://www.ncbi.nlm.nih.gov/pubmed/21202493 http://dx.doi.org/10.1107/S1600536808013688 |
Sumario: | The title coordination polymer, [Zn(C(8)H(4)N(4)O(2))(H(2)O)](n), was prepared by the hydrothermal reaction of zinc nitrate and 2-(1H-tetrazol-5-yl)benzoic acid. Two types of coordinated zinc cations exist in the structure. One is tetrahedrally coordinated by two O and two N from two ligands, the other is octahedrally coordinated by two N and two O from two ligands at equatorial sites and by two O atoms of water molecules at axial sites, resulting in a two-dimensional framework. The crystal structure is stabilized by intramolecular O—H⋯O and O—H⋯N hydrogen bonds. |
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