Poly[aqua­[μ(3)-5-(2-carboxyl­atophen­yl)-1H-tetra­zolato]zinc(II)]

The title coordination polymer, [Zn(C(8)H(4)N(4)O(2))(H(2)O)](n), was prepared by the hydro­thermal reaction of zinc nitrate and 2-(1H-tetra­zol-5-yl)benzoic acid. Two types of coordinated zinc cations exist in the structure. One is tetra­hedrally coordinated by two O and two N from two ligands, the...

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Detalles Bibliográficos
Autores principales: Li, Xiu-Zhi, Qu, Zhi-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961416/
https://www.ncbi.nlm.nih.gov/pubmed/21202493
http://dx.doi.org/10.1107/S1600536808013688
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author Li, Xiu-Zhi
Qu, Zhi-Rong
author_facet Li, Xiu-Zhi
Qu, Zhi-Rong
author_sort Li, Xiu-Zhi
collection PubMed
description The title coordination polymer, [Zn(C(8)H(4)N(4)O(2))(H(2)O)](n), was prepared by the hydro­thermal reaction of zinc nitrate and 2-(1H-tetra­zol-5-yl)benzoic acid. Two types of coordinated zinc cations exist in the structure. One is tetra­hedrally coordinated by two O and two N from two ligands, the other is octa­hedrally coordinated by two N and two O from two ligands at equatorial sites and by two O atoms of water mol­ecules at axial sites, resulting in a two-dimensional framework. The crystal structure is stabilized by intra­molecular O—H⋯O and O—H⋯N hydrogen bonds.
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spelling pubmed-29614162010-12-30 Poly[aqua­[μ(3)-5-(2-carboxyl­atophen­yl)-1H-tetra­zolato]zinc(II)] Li, Xiu-Zhi Qu, Zhi-Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title coordination polymer, [Zn(C(8)H(4)N(4)O(2))(H(2)O)](n), was prepared by the hydro­thermal reaction of zinc nitrate and 2-(1H-tetra­zol-5-yl)benzoic acid. Two types of coordinated zinc cations exist in the structure. One is tetra­hedrally coordinated by two O and two N from two ligands, the other is octa­hedrally coordinated by two N and two O from two ligands at equatorial sites and by two O atoms of water mol­ecules at axial sites, resulting in a two-dimensional framework. The crystal structure is stabilized by intra­molecular O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2008-05-14 /pmc/articles/PMC2961416/ /pubmed/21202493 http://dx.doi.org/10.1107/S1600536808013688 Text en © Li and Qu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Xiu-Zhi
Qu, Zhi-Rong
Poly[aqua­[μ(3)-5-(2-carboxyl­atophen­yl)-1H-tetra­zolato]zinc(II)]
title Poly[aqua­[μ(3)-5-(2-carboxyl­atophen­yl)-1H-tetra­zolato]zinc(II)]
title_full Poly[aqua­[μ(3)-5-(2-carboxyl­atophen­yl)-1H-tetra­zolato]zinc(II)]
title_fullStr Poly[aqua­[μ(3)-5-(2-carboxyl­atophen­yl)-1H-tetra­zolato]zinc(II)]
title_full_unstemmed Poly[aqua­[μ(3)-5-(2-carboxyl­atophen­yl)-1H-tetra­zolato]zinc(II)]
title_short Poly[aqua­[μ(3)-5-(2-carboxyl­atophen­yl)-1H-tetra­zolato]zinc(II)]
title_sort poly[aqua­[μ(3)-5-(2-carboxyl­atophen­yl)-1h-tetra­zolato]zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961416/
https://www.ncbi.nlm.nih.gov/pubmed/21202493
http://dx.doi.org/10.1107/S1600536808013688
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AT quzhirong polyaquam352carboxylatophenyl1htetrazolatozincii

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