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7-Bromo-2-methyl-1-tosylnaphtho[2,1-b]furan
The title compound, C(20)H(15)BrO(3)S, was prepared by the oxidation of 7-bromo-2-methyl-1-(4-tolylsulfanyl)naphtho[2,1-b]furan with 3-chloroperoxybenzoic acid. The 4-tolyl ring makes a dihedral angle of 70.96 (6)° with the plane of the naphthofuran fragment. The crystal structure is stabilized...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961428/ https://www.ncbi.nlm.nih.gov/pubmed/21202666 http://dx.doi.org/10.1107/S1600536808015286 |
Sumario: | The title compound, C(20)H(15)BrO(3)S, was prepared by the oxidation of 7-bromo-2-methyl-1-(4-tolylsulfanyl)naphtho[2,1-b]furan with 3-chloroperoxybenzoic acid. The 4-tolyl ring makes a dihedral angle of 70.96 (6)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by aromatic π–π stacking interactions, with centroid–centroid distances of 3.672 (3) and 3.858 (3) Å between the central benzene and furan rings, and between the brominated benzene and central benzene rings of the naphthofuran system of neighbouring molecules, respectively. In addition, the stacked molecules exhibit C—H⋯π and inter- and intramolecular C—H⋯O interactions. |
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