catena-Poly[[bis­[(2-carboxy­benzoato-κO)silver(I)](Ag—Ag)]bis­(μ-isonicotinic acid-κ(2) N:O)]

The title compound, [Ag(C(8)H(5)O(4))(C(6)H(5)NO(2))](n), contains one Ag(I) atom, one phthalate ligand and one isonicotinic acid mol­ecule in the asymmetric unit. Each Ag atom is three-coordinated in a T-shaped geometry by two O atoms and one N atom from one phthalate ligand and two isonicotinic ac...

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Detalles Bibliográficos
Autores principales: Li, Xiao-Feng, An, Yan, Yin, Yan-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961433/
https://www.ncbi.nlm.nih.gov/pubmed/21202469
http://dx.doi.org/10.1107/S1600536808009586
Descripción
Sumario:The title compound, [Ag(C(8)H(5)O(4))(C(6)H(5)NO(2))](n), contains one Ag(I) atom, one phthalate ligand and one isonicotinic acid mol­ecule in the asymmetric unit. Each Ag atom is three-coordinated in a T-shaped geometry by two O atoms and one N atom from one phthalate ligand and two isonicotinic acid ligands. The isonicotinic acid ligand bridges two Ag atoms, forming a one-dimensional chain. Adjacent chains are linked by Ag—Ag inter­actions, leading to a double-chain. These double-chains are further linked via hydrogen bonds into a two-dimensional layer.

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