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Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) N-bis­{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II)

In the title compound, [Mn(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Mn(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], each Mn(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water mol­ecule to give a slightly dist...

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Detalles Bibliográficos
Autores principales: Sun, Zhen-Hai, Yang, Gui-Bin, Meng, Ling-Bo, Chen, Shen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961441/
https://www.ncbi.nlm.nih.gov/pubmed/21202472
http://dx.doi.org/10.1107/S1600536808012749
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author Sun, Zhen-Hai
Yang, Gui-Bin
Meng, Ling-Bo
Chen, Shen
author_facet Sun, Zhen-Hai
Yang, Gui-Bin
Meng, Ling-Bo
Chen, Shen
author_sort Sun, Zhen-Hai
collection PubMed
description In the title compound, [Mn(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Mn(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], each Mn(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water mol­ecule to give a slightly distorted octa­hedral geometry. Two such Mn(III) ions are linked by a square-planar Ni(CN)(4) unit, which lies on an inversion centre. A two-dimensional network is formed by O—H⋯O and O—H⋯N hydrogen bonds.
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spelling pubmed-29614412010-12-30 Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) N-bis­{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II) Sun, Zhen-Hai Yang, Gui-Bin Meng, Ling-Bo Chen, Shen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Mn(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], each Mn(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water mol­ecule to give a slightly distorted octa­hedral geometry. Two such Mn(III) ions are linked by a square-planar Ni(CN)(4) unit, which lies on an inversion centre. A two-dimensional network is formed by O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961441/ /pubmed/21202472 http://dx.doi.org/10.1107/S1600536808012749 Text en © Sun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Zhen-Hai
Yang, Gui-Bin
Meng, Ling-Bo
Chen, Shen
Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) N-bis­{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II)
title Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) N-bis­{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II)
title_full Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) N-bis­{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II)
title_fullStr Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) N-bis­{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II)
title_full_unstemmed Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) N-bis­{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II)
title_short Diaqua-1κO,3κO-di-μ-cyanido-1:2κ(2) N:C;2:3κ(2) C:N-dicyanido-2κ(2) N-bis­{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}-1κ(4) O,N,N′,O′;3κ(4) O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II)
title_sort diaqua-1κo,3κo-di-μ-cyanido-1:2κ(2) n:c;2:3κ(2) c:n-dicyanido-2κ(2) n-bis­{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}-1κ(4) o,n,n′,o′;3κ(4) o,n,n′,o′-1,3-dimanganese(iii)-2-nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961441/
https://www.ncbi.nlm.nih.gov/pubmed/21202472
http://dx.doi.org/10.1107/S1600536808012749
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